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@INPROCEEDINGS{Im:1050504,
author = {Im, Eunmi and Durmus, Yasin Emre and Tempel, Hermann and
Eichel, Rüdiger-A.},
title = {{U}nveiling {I}ron-{S}lurry/{A}ir {B}atteries: {A} {H}ybrid
{A}pproach {I}ntegrating {I}ron-{A}ir and {F}low {B}attery
{S}ystems},
reportid = {FZJ-2026-00272},
year = {2025},
note = {BMBF 13XP0536B- Gekapselte Eisenmaterialien für
Eisen-Slurry/Luft-Akkumulatoren zur stationären
Energiespeicherung mit hoher Kapazität (02.2023-06.2026)},
abstract = {The increasing demand for renewable energy sources, such as
wind and solar, is driving the need for efficient and
sustainable energy storage systems. Among the promising
alternatives to conventional batteries, iron-air batteries
have gained significant attention due to their high energy
densities (2,500 WhL-1), intrinsic safety, environmental
friendliness, and reliance on abundant materials. However, a
key challenge with traditional iron-air batteries is the
solid iron electrode, where surface passivation caused by
oxidation products limits charge transport and leads to
extended formation cycles. Therefore, the development of
iron electrodes with a high loading of active material to
enhance storage capacity, while ensuring efficient charge
transport at practical current densities, is essential to
fully unlock the potential of iron-air batteries.This study
focuses on the investigation of iron-slurry/air battery
designed to combine the advantages of conventional iron-air
batteries with the design flexibility of flow batteries,
enabling independent control of energy capacity and power
output. Iron-coated carbon powder was initially synthesized
as an active material, where conductive carbon particles
facilitate electron transport. Key parameters such as iron
content (to maximize capacity) and slurry viscosity (to
ensure efficient flow and pumping) were optimized. The
synthesized slurry was then characterized using X-ray
diffraction (XRD) for phase identification, while
morphological and elemental analyses were conducted using
transmission electron microscopy (TEM), scanning electron
microscopy (SEM), and inductively coupled plasma-optical
emission spectroscopy (ICP-OES). Electrochemical behavior
was evaluated through open circuit potential (OCP), cyclic
voltammetry (CV), and chronopotentiometry (CP) measurements.
Based on these physical and electrochemical
characterizations, the optimized slurry formulation was
selected and mixed with an alkaline electrolyte (KOH
solution) to fabricate the iron slurry electrodes. A
proof-of-concept iron-slurry/air battery was demonstrated
for the first time, offering clear evidence of the
system’s practical viability. This demonstration provides
critical insight into the potential of slurry-based battery
systems and suggests a viable pathway towards enhanced
sustainability and efficiency in renewable energy storage
applications.},
month = {Sep},
date = {2025-09-07},
organization = {76th Annual meeting of the
International Society of
Electrochemistry, Mainz (Germany), 7
Sep 2025 - 12 Sep 2025},
subtyp = {Other},
cin = {IET-1},
cid = {I:(DE-Juel1)IET-1-20110218},
pnm = {1223 - Batteries in Application (POF4-122)},
pid = {G:(DE-HGF)POF4-1223},
typ = {PUB:(DE-HGF)24},
url = {https://juser.fz-juelich.de/record/1050504},
}