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@INPROCEEDINGS{Liu:1050746,
author = {Liu, Jialiang and Fröhlich, Kristina and Karl, André and
Jodat, Eva and Eichel, Rüdiger-A.},
title = {{A}dhesion force analysis on {PEM} water electrolysis
materials},
reportid = {FZJ-2026-00489},
year = {2025},
abstract = {Proton Exchange Membrane Water Electrolysis (PEMWE)
presents a promising solution for the direct integration of
hydrogen production with renewable solar or wind energy due
to its rapid response performance [1]. However, at high
current densities, the accumulation of gas products within
the catalyst layer can obstruct the connection between water
molecules and the catalyst in the Membrane Electrode
Assembly (MEA). This phenomenon leads to an increase of
overpotential, thereby reducing the overall efficiency of
electrochemical performance [2].Investigating the effect of
the surface structure and composition of the catalyst layer
on gas bubble adsorption can help to better understand and
to reduce this phenomenon. The adhesion force between the
gas bubble and the electrode can be used as a benchmark to
evaluate the ease of bubble detachment. Several previous
studies have explored this topic in other research fields,
for instance, Ren et al. demonstrate that a modification of
nickel electrode surfaces with nanocone structures increases
the surface roughness, thereby enhancing gas bubble
detachment and improving efficiency in high-rate alkaline
water splitting [3]. However, further in-depth investigation
is still needed in the field of PEMWE.In this work, we
present the results of adhesion force measurements performed
on proton conductive membranes, catalyst electrodes and
MEAs. Experiments were carried out with a tensiometer using
water and oxygen as analytes. It was shown that parameters
such as the membrane thickness, catalyst material, loading,
structure and different treatment procedures of the analyzed
sample can have a significant effect on the adhesion
force.Funding: This work was financially supported by the
Bundesministerium für Bildung und Forschung (BMBF):
Wasserstoff - Leitprojekt H2Giga, Teilvorhaben DERIEL
(project number 03HY122C), SEGIWA (project number
03HY121B).[1] Wang, Y., Pang, Y., Xu, H., Martinez, A. $\&$
Chen, K. S. Energy Environ. Sci. 2022, 15, 2288–2328.[2]
Yuan, S. et al. Prog. Energy Combust. Sci. 2023, 96,
101075.[3] Q. Ren, L. Feng, C. Ye, X. Xue, D. Lin, S.
Eisenberg, T. Kou, E. B. Duoss, C. Zhu and Y. Li, Adv.
Energy Mater. 2023, 13, 2302073.},
month = {Sep},
date = {2025-09-07},
organization = {76th Annual Meeting of the
International Society of
Electrochemistry, Mainz (Germany), 7
Sep 2025 - 12 Sep 2025},
subtyp = {Other},
cin = {IET-1},
cid = {I:(DE-Juel1)IET-1-20110218},
pnm = {1231 - Electrochemistry for Hydrogen (POF4-123) / HITEC -
Helmholtz Interdisciplinary Doctoral Training in Energy and
Climate Research (HITEC) (HITEC-20170406)},
pid = {G:(DE-HGF)POF4-1231 / G:(DE-Juel1)HITEC-20170406},
typ = {PUB:(DE-HGF)24},
url = {https://juser.fz-juelich.de/record/1050746},
}