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| Hauptseite > Publikationsdatenbank > Tape Casting of NASICON-Based Separators with High Conductivity for Na All-Solid-State Batteries > print |
| Hauptseite > Publikationsdatenbank > Tape Casting of NASICON-Based Separators with High Conductivity for Na All-Solid-State Batteries > print |
| 001 | 1050780 | ||
| 005 | 20260116204419.0 | ||
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| 100 | 1 | _ | |a Rosen, Melanie |0 P:(DE-Juel1)173936 |b 0 |
| 245 | _ | _ | |a Tape Casting of NASICON-Based Separators with High Conductivity for Na All-Solid-State Batteries |
| 260 | _ | _ | |a Basel |c 2025 |b MDPI |
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| 520 | _ | _ | |a Sodium–ion batteries are emerging as strong competition to lithium–ion batteries in certain market sections. While these cells do not use critical raw materials, they still feature a liquid electrolyte with all its inherent safety issues, like high flammability and toxicity. Alternative concepts like oxide-ceramic-based all-solid-state batteries feature the highest possible safety while still maintaining competitive electrochemical performance. However, production technologies are still in their infancy, especially for Na all-solid-state batteries, and need to be urgently developed to enable solid-state-battery technology using only abundant raw materials. In this study, the additive-free production of freestanding, undoped NaSICON separators via tape-casting is demonstrated, having an extremely high total Na-ion conductivity of up to 2.44 mS·cm−1 at room temperature. Nevertheless, a strong influence of sample thickness on phase purity as well as electrochemical performance is uncovered. Additionally, the effect of self-coating of NaSICON during high-temperature treatment was evaluated as a function of thickness. While advantageous for increasing the stability against Na-metal anodes, detrimental consequences are identified when separator thickness is reduced to industrially relevant values and mitigation measures are postulated. |
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| 773 | _ | _ | |a 10.3390/electrochem6010005 |g Vol. 6, no. 1, p. 5 - |0 PERI:(DE-600)3028307-3 |n 1 |p 5 - |t Electrochem |v 6 |y 2025 |x 2673-3293 |
| 856 | 4 | _ | |u https://juser.fz-juelich.de/record/1050780/files/electrochem-06-00005-v2.pdf |y OpenAccess |
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