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@PHDTHESIS{Petzold:10515,
author = {Petzold, Katja},
title = {{Z}ur {K}limatologie von {S}tickoxiden, {O}zon und
{K}ohlenmonoxid in der {T}roposphäre: eine {A}nalyse des
{MOZAIC}-{D}atensatzes},
volume = {4327},
school = {RWTH Aachen},
type = {Dr. (Univ.)},
address = {Jülich},
publisher = {Forschungszentrum Jülich GmbH Zentralbibliothek, Verlag},
reportid = {PreJuSER-10515, Juel-4327},
series = {Berichte des Forschungszentrums Jülich},
pages = {VIII, 185 p.},
year = {2010},
note = {Record converted from VDB: 12.11.2012; Aachen, RWTH, Diss.,
2010},
abstract = {Tropospheric ozone is an effective greenhouse gas in the
tropopause region. Near the surface it is toxic for humans
and the ecosystem. It is produced by precursors nitrogen
oxides, carbon monoxide, and hydrocarbons, so called
volatile organic compounds. Stratospheric ozone protects the
earth surface from shortwave radiation and is built by
photolysis of oxygen. Within the scope of the EU-funded
Project MOZAIC (Measurement of ozone, water vapor, carbon
monoxide, and nitrogen oxides by Airbus in-service
aircraft)measurements made since 1994 aboard five A-340 long
range aircraft on scheduled flights around the globe provide
useful information on air quality in the environment of many
cities. With the work at hand the trace gas concentrations
of ozone, nitrogen oxides, and carbon monoxide are analysed
from a geographical point of view. An introduction to the
emission patterns of the relevant trace gases, tropospheric
ozone chemistry, and the atmospheric circulation as well as
an overview of the MOZAIC project is followed by a regard of
the upper troposphere first. Some regions in the tropopause
region are highlighted by higher Ozone and nitrogen oxides
than others. Carbon monoxide shows a minor spatial
variability and is well mixed. As a potential source of
nitrogen oxides and carbon monoxide three case studies are
examined on the influence of lightning and convection. A
strong correlation is found for nitrogen oxides and carbon
monoxide in case of convection which shows evidence of
boundary layer sources for both trace gases. Nitrogen oxides
only are enhanced in case of intense lightning. The
correlation with carbon monoxide is weak. The findings point
to a strong influence of the synoptic situation on trace gas
concentrations in the upper troposphere. High concentrations
of ozone and nitrogen oxides occur over eastern North
America and eastern Asia as well as over the Arabian
peninsular. These regions belong to characteristic climate
zones. Therefore the relevant MOZAIC airports are grouped to
the climate zones developed by Koeppen and recently revised
by Kottek et al. (2006). Vertical profiles of ozone show
similarities in between the climes. The extratropical
midlatitudes show differences between the eastern and
western parts of the continents. Low ozone concentrations in
summer 10 - 12 km altitude indicate a higher tropopause in
the eastern parts with higher temperatures in summer. A
further look is taken on seasonal wind roses for surface and
free troposphere. There is evidence that the concentrations
of ozone and carbon monoxide in the vicinity of the chosen
airports is determined by wind direction. High carbon
monoxide burden comes along with lower ozone concentrations.
Further the annual cycles of the different trace gases are
examined at several altitude levels. The water vapour mixing
ratio reveals the wet and dry seasons in the tropics as well
as the difference between western and eastern parts of the
continent. The latter shows higher concentrations and a
[...]},
cin = {ICG-2},
cid = {I:(DE-Juel1)VDB791},
pnm = {Atmosphäre und Klima},
pid = {G:(DE-Juel1)FUEK406},
typ = {PUB:(DE-HGF)11},
url = {https://juser.fz-juelich.de/record/10515},
}