% IMPORTANT: The following is UTF-8 encoded.  This means that in the presence
% of non-ASCII characters, it will not work with BibTeX 0.99 or older.
% Instead, you should use an up-to-date BibTeX implementation like “bibtex8” or
% “biber”.

@ARTICLE{Saur:1052074,
      author       = {Saur, Katharina Maria and Fridley, Nina A. and Gausmann,
                      Marcel and Jupke, Andreas},
      title        = {{B}eyond {P}hase {E}quilibria: {S}electing {S}uitable
                      {S}olvent {S}ystems for {R}eactive {E}xtraction of
                      {C}arboxylic {A}cids},
      journal      = {Annual review of chemical and biomolecular engineering},
      volume       = {16},
      number       = {1},
      issn         = {1947-5438},
      address      = {Palo Alto, Calif.},
      publisher    = {Annual Reviews},
      reportid     = {FZJ-2026-00743},
      pages        = {23 - 58},
      year         = {2025},
      abstract     = {Reactive extraction is an attractive separation technology
                      that can replace energy-intensive water evaporation steps in
                      the industrial production of carboxylic acids. We
                      systematically review the current literature on the
                      extraction of low-value bioproducts and thereby identify the
                      reduced availability of predictive models, limited
                      selectivity, and challenging phase separation as possible
                      bottlenecks in the industrial implementation of reactive
                      extraction. Furthermore, we discuss requirements and
                      strategies for closing the material cycles for batch and
                      continuous processes. With these challenges in mind, we
                      analyze the most widely used extractants (trioctylamine,
                      trioctylphosphine oxide, and tributyl phosphate) in
                      combination with common diluents (e.g., long-chain alcohols
                      and alkanes) in terms of their ability to meet process
                      needs. We illustrate the subordinate role of equilibrium
                      constants in overall process design while emphasizing the
                      potential for flexible reactive extraction systems tailored
                      to process requirements.},
      cin          = {IBG-2},
      ddc          = {540},
      cid          = {I:(DE-Juel1)IBG-2-20101118},
      pnm          = {2172 - Utilization of renewable carbon and energy sources
                      and engineering of ecosystem functions (POF4-217) / BMBF
                      031B0918E - $BioökonomieREVIER_INNO:$ Entwicklung der
                      Modellregion BioökonomieREVIER Rheinland, TP E: Upcycling
                      organischer Reststoffe für die chemische Industrie (UpRePP)
                      (BMBF-031B0918E)},
      pid          = {G:(DE-HGF)POF4-2172 / G:(DE-82)BMBF-031B0918E},
      typ          = {PUB:(DE-HGF)16},
      doi          = {10.1146/annurev-chembioeng-082323-120010},
      url          = {https://juser.fz-juelich.de/record/1052074},
}