001     1052276
005     20260223122501.0
024 7 _ |a 10.1039/D5EE01722J
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024 7 _ |a 1754-5692
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024 7 _ |a 1754-5706
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024 7 _ |a 10.34734/FZJ-2026-00893
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037 _ _ |a FZJ-2026-00893
082 _ _ |a 690
100 1 _ |a Qiu, Shudi
|0 0000-0002-3005-5788
|b 0
245 _ _ |a Over one-micron-thick void-free perovskite layers enable highly efficient and fully printed solar cells
260 _ _ |a Cambridge
|c 2025
|b RSC Publ.
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520 _ _ |a Commercialization of perovskite photovoltaics hinges on the successful transition from laboratory-scale fabrication to industrial-scale manufacturing. A key challenge in fully printed perovskite solar cells with non-reflecting back electrodes is the deposition of high-quality, over-one-micron-thick perovskite layers to minimize photocurrent losses from incomplete light absorption. However, the formation of voids at the substrate/perovskite interface impedes the fabrication of such layers. Here, phase-field simulations reveal that the bottom voids originate from trapped residual solvents, driven by nanocrystal aggregation at the liquid–vapor interface during drying. Guided by these insights, we introduce a two-dimensional (2D) perovskite layer-assisted growth strategy to promote heterogeneous nucleation at the substrate, accelerating 3D perovskite crystallization and preventing solvent entrapment. This strategy enables the formation of highly crystalline, monolithic perovskite films exceeding one micrometer in thickness. The resulting void-free films maximize photocurrent extraction, achieving power conversion efficiencies of 19.9% on rigid substrates and 17.5% on flexible substrates in fully printed perovskite solar cells with non-reflecting carbon electrodes.
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536 _ _ |a DFG project G:(GEPRIS)506698391 - Experimentelle und theoretische Untersuchungen von Prozessparametern zur Herstellung dicker und defektfreier Perowskit-Schichten (506698391)
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700 1 _ |a Majewski, Martin
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700 1 _ |a Dong, Lirong
|0 0000-0002-6018-5946
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700 1 _ |a Distler, Andreas
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700 1 _ |a Li, Chaohui
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700 1 _ |a Forberich, Karen
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700 1 _ |a Tian, Jingjing
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700 1 _ |a Hemasiri, Naveen Harindu
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700 1 _ |a Liu, Chao
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700 1 _ |a Zhang, Jiyun
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700 1 _ |a Yang, Fu
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700 1 _ |a Le Corre, Vincent M.
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700 1 _ |a Bibrack, Max
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700 1 _ |a Basu, Robin
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700 1 _ |a Barabash, Anastasia
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700 1 _ |a Harting, Jens
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700 1 _ |a Ronsin, Olivier J. J.
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700 1 _ |a Du, Tian
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700 1 _ |a Egelhaaf, Hans-Joachim
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700 1 _ |a Brabec, Christoph J.
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773 _ _ |a 10.1039/D5EE01722J
|g Vol. 18, no. 12, p. 5926 - 5939
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