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@INPROCEEDINGS{Stroyuk:1052820,
author = {Stroyuk, Oleksandr and Raievska, Oleksandra and Kinge,
Sachin and Hauch, Jens and Brabec, Christoph},
title = {{I}nnovative {A}pproach to {B}ismuth-{A}ntimony-{I}odide
{D}ouble {P}erovskite {PV} {A}bsorbers via {A}nion
{E}xchange and {S}olide-{S}tate {R}eactions42nd {E}uropean
{P}hotovoltaic {S}olar {E}nergy {C}onference and
{E}xhibition},
publisher = {WIP-Munich},
reportid = {FZJ-2026-01177},
pages = {579 kB4 pages},
year = {2025},
abstract = {This work focuses on the development of advanced synthesis
protocols for lead-free Cs2AgBi(Sb)Br6 perovskites and their
conversion into lower-bandgap Cs2AgBi(Sb)I6 perovskite PV
absorbers by using an innovative combination of mild anion
exchange with a solid-state reaction between intermediate
iodide derivatives. High-throughput robot-assisted
experimentation is applied for the optimization of the
synthesis conditions, targeting the highest yields of
Cs2AgBi(Sb)I6 perovskites (ca. 90 $mass\%)$ with the lowest
bandgap (1.78 eV). We provide new insights into the
pathways, mechanisms, and dynamics of the formation of
iodide double perovskites, reporting stable lead-free double
iodide perovskites crystallized in a non-conventional
tetragonal symmetry.},
month = {Sep},
date = {2025-09-22},
organization = {42nd European Photovoltaic Solar
Energy Conference and Exhibition,
Bilbao (Spanien), 22 Sep 2025 - 26 Sep
2025},
keywords = {Thin-Films and New Concepts (Other) / Perovskites (Other)},
cin = {IET-2},
cid = {I:(DE-Juel1)IET-2-20140314},
pnm = {1212 - Materials and Interfaces (POF4-121)},
pid = {G:(DE-HGF)POF4-1212},
typ = {PUB:(DE-HGF)8},
doi = {10.4229/EUPVSEC2025/2DO.8.3},
url = {https://juser.fz-juelich.de/record/1052820},
}