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@ARTICLE{Lugovy:10570,
author = {Lugovy, M. and Slyunyayev, V. and Steinberger-Wilckens, R.},
title = {{M}icrocracking in {E}lectron-{B}eam {D}eposited
{S}candia-{S}tabilised {Z}irconia {E}lectrolyte.},
journal = {Journal of power sources},
volume = {194},
issn = {0378-7753},
address = {New York, NY [u.a.]},
publisher = {Elsevier},
reportid = {PreJuSER-10570},
pages = {950 - 960},
year = {2009},
note = {The work was supported by INTAS Grant No. 06-1000024-8748
"Structure Optimization of SOFC Based on Scandia Doped
Zirconia Ceramics for Space Application". We thank Dr. L.
Dubykivskyy, Mr. Y. Brodnikovskyy and Mr. M. Brychevskyy
from Institute for Problems of Materials Science, Kiev,
Ukraine for half-cell fabrication and annealing, Dr. P.
Batfalsky, Forschungszentrum Juelich, Germany, for Scanning
Electron Microscopy, Dr. J. Malzbender, Forschungszentrum
Juelich, Germany, for biaxial bending tests, Dr. R.W.
Steinbrech, Forschungszentrum Juelich, Germany for helpful
discussion.},
abstract = {It is the aim of the present work to address some of the
aspects of microcracking in electron beam deposited
scandia-stabilised zirconia electrolyte applied for solid
oxide fuel cells (SOFC) where a thin electrolyte layer is
deposited on a relatively thick anode substrate. A model of
microcracking for the electrolyte material is proposed which
takes into account the statistical distribution of grain
sizes, the stress redistribution due to failure of
individual structural elements as well as the local
criterion of grain fracture. The combination of electron
microscopy research with model calculations permits both the
specific energy of new surface creation in the electrolyte
and critical parameters of the microcracking process to be
determined. The annealing-induced electrolyte microcracking
discussed in this work corresponds to localised
microcracking, where each next structural element fails
mainly at an existing microcrack tip. The features of
localised microcracking in electron beam deposited
scandia-stabilised zirconia electrolyte are analysed. (C)
2009 Elsevier B.V. All rights reserved.},
keywords = {J (WoSType)},
cin = {IEF-PBZ / JARA-ENERGY},
ddc = {620},
cid = {I:(DE-Juel1)VDB816 / $I:(DE-82)080011_20140620$},
pnm = {Rationelle Energieumwandlung},
pid = {G:(DE-Juel1)FUEK402},
shelfmark = {Electrochemistry / Energy $\&$ Fuels},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000270620500048},
doi = {10.1016/j.jpowsour.2009.05.024},
url = {https://juser.fz-juelich.de/record/10570},
}