TY - JOUR
AU - Brunger, A.T.
AU - Adams, P.D.
AU - Fromme, P.
AU - Fromme, R.
AU - Levitt, M.
AU - Schröder, G.F.
TI - Improving the accuracy of macromolecular structure refinement at 7 Å resolution
JO - Structure
VL - 20
SN - 0969-2126
CY - London [u.a.]
PB - Elsevier Science
M1 - PreJuSER-111909
SP - 957 - 966
PY - 2012
N1 - Record converted from VDB: 16.11.2012
AB - In X-ray crystallography, molecular replacement and subsequent refinement is challenging at low resolution. We compared refinement methods using synchrotron diffraction data of photosystem I at 7.4 Å resolution, starting from different initial models with increasing deviations from the known high-resolution structure. Standard refinement spoiled the initial models, moving them further away from the true structure and leading to high R(free)-values. In contrast, DEN refinement improved even the most distant starting model as judged by R(free), atomic root-mean-square differences to the true structure, significance of features not included in the initial model, and connectivity of electron density. The best protocol was DEN refinement with initial segmented rigid-body refinement. For the most distant initial model, the fraction of atoms within 2 Å of the true structure improved from 24% to 60%. We also found a significant correlation between R(free) values and the accuracy of the model, suggesting that R(free) is useful even at low resolution.
KW - Bacterial Proteins: chemistry
KW - Crystallography, X-Ray
KW - Models, Molecular
KW - Photosystem I Protein Complex: chemistry
KW - Protein Structure, Secondary
KW - Protein Structure, Tertiary
KW - Software
KW - Structural Homology, Protein
KW - Bacterial Proteins (NLM Chemicals)
KW - Photosystem I Protein Complex (NLM Chemicals)
LB - PUB:(DE-HGF)16
C6 - pmid:22681901
C2 - pmc:PMC3380535
UR - <Go to ISI:>//WOS:000305094500004
DO - DOI:10.1016/j.str.2012.04.020
UR - https://juser.fz-juelich.de/record/111909
ER -