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@ARTICLE{Perlt:111941,
author = {Perlt, S. and Höche, Th. and Dadda, J. and Müller, E. and
Bauer Pereira, P. and Hermann, R. and Sarahan, M. and
Pippel, E. and Brydson, R.},
title = {{M}icrostructure analyses and thermoelectric properties of
{A}g1-x{P}b18{S}b1+y{T}e20},
journal = {Journal of solid state chemistry},
volume = {193},
issn = {0022-4596},
address = {Orlando, Fla.},
publisher = {Academic Press},
reportid = {PreJuSER-111941},
pages = {58 - 63},
year = {2012},
note = {The authors would like to thank the BMBF (Contract 03X3540)
for funding this study. S. Perlt thanks the Leibniz
Institute of Surface Modification for financial support
enabling research visits at UK facilities. Contributions by
B. Schaffer and Q. Ramasse (both SuperSTEM facility
Daresbury Laboratories, UK) are gratefully acknowledged. T.
Hoche is endepted to Dr. P. Werner granting access to TEM
facilities at MPI for Microstructure Physics in Halle.},
abstract = {This study reports microstructural investigations of
long-term annealed Ag1-xPbmSb1+yTe2+m (m=18, x=y=0,
hereinafter referred to as AgPb18SbTe20)
(Lead-Antimony-Silver-Tellurium, LAST-18) as well as of
Ag1-xPb18Sb1+yTe20, i.e. Ag-deficient and Sb-excess LAST-18
(x not equal 0, y not equal 0), respectively. Two different
length scales are explored. The micrometer scale was
evaluated by SEM to analyze the volume fraction and the
number of secondary phases as well as the impact of
processing parameters on the homogeneity of bulk samples.
For AgPb18SbTe20, site-specific FIB liftout of TEM lamellae
from thermoelectrically characterized samples was
accomplished to investigate the structure on the nanometer
scale. High-resolution TEM and energy-filtered TEM were
performed to reveal shape and size distribution of
nanoprecipitates, respectively. A hypothesis concerning the
structure-property relationship is set out within the frame
of a gradient annealing experiment. This study is completed
by results dealing with inhomogeneities on the micrometer
scale of Ag1-xPb18Sb1+yTe20 and its electronic properties.
(C) 2012 Elsevier Inc. All rights reserved.},
keywords = {J (WoSType)},
cin = {PGI-4 / JCNS-2 / JARA-FIT},
ddc = {540},
cid = {I:(DE-Juel1)PGI-4-20110106 / I:(DE-Juel1)JCNS-2-20110106 /
$I:(DE-82)080009_20140620$},
pnm = {Grundlagen für zukünftige Informationstechnologien
(FUEK412) / 544 - In-house Research with PNI (POF2-544)},
pid = {G:(DE-Juel1)FUEK412 / G:(DE-HGF)POF2-544},
shelfmark = {Chemistry, Inorganic $\&$ Nuclear / Chemistry, Physical},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000308047800012},
doi = {10.1016/j.jssc.2012.03.064},
url = {https://juser.fz-juelich.de/record/111941},
}