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@ARTICLE{Puttock:111945,
author = {Puttock, A. and Dungait, J.A.J. and Bol, R. and Dixon, E.R.
and Macleod, C.J.A. and Brazier, R.E.},
title = {{S}table carbon isotope analysis of fluvial sediment fluxes
over two contrasting {C}4-{C}3 semi-arid vegetation
transitions},
journal = {Rapid communications in mass spectrometry},
volume = {26},
issn = {0951-4198},
address = {New York, NY},
publisher = {Wiley Interscience},
reportid = {PreJuSER-111945},
pages = {2386 - 2392},
year = {2012},
note = {This research was supported by the University of Exeter and
Rothamsted Research at North Wyke, NSF award DEB-0217774 to
the University of New Mexico for Long-term Ecological
Research and a British Society for Geomorphology student
travel grant. This work represents part of the BBSRC-funded
programmes at Rothamsted Research on Sustainable Soil
Function and Bioenergy and Climate Change. Additional thanks
go to everyone from the Sevilleta LTER/USFWS who made
fieldwork for this research possible and enjoyable. Finally,
thanks go to the anonymous reviewers for their helpful
feedback which improved the manuscript.},
abstract = {Globally, many drylands are experiencing the encroachment
of woody vegetation into grasslands. These changes in
ecosystem structure and processes can result in increased
sediment and nutrient fluxes due to fluvial erosion. As
these changes are often accompanied by a shift from C(4) to
C(3) vegetation with characteristic δ(13) C values, stable
isotope analysis provides a promising mechanism for tracing
these fluxes.Input vegetation, surface sediment and
fluvially eroded sediment samples were collected across two
contrasting C(4) -C(3) dryland vegetation transitions in New
Mexico, USA. Isotope ratio mass spectrometric analyses were
performed using a Carlo Erba NA2000 analyser interfaced to a
SerCon 20-22 isotope ratio mass spectrometer to determine
bulk δ(13) C values.Stable isotope analyses of contemporary
input vegetation and surface sediments over the monitored
transitions showed significant differences (p <0.05) in the
bulk δ(13) C values of C(4) Bouteloua sp. (grama)
grassland, C(3) Larrea tridentata (creosote) shrubland and
C(3) Pinus edulis/Juniperus monosperma (piñon-juniper)
woodland sites. Significantly, this distinctive δ(13) C
value was maintained in the bulk δ(13) C values of
fluvially eroded sediment from each of the sites, with no
significant variation between surface sediment and eroded
sediment values.The significant differences in bulk δ(13) C
values between sites were dependent on vegetation input.
Importantly, these values were robustly expressed in
fluvially eroded sediments, suggesting that stable isotope
analysis is suitable for tracing sediment fluxes. Due to the
prevalent nature of these dryland vegetation transitions in
the USA and globally, further development of stable isotope
ratio mass spectrometry has provided a valuable tool for
enhanced understanding of functional changes in these
ecosystems.},
keywords = {J (WoSType)},
cin = {IBG-3},
ddc = {530},
cid = {I:(DE-Juel1)IBG-3-20101118},
pnm = {Terrestrische Umwelt},
pid = {G:(DE-Juel1)FUEK407},
shelfmark = {Biochemical Research Methods / Chemistry, Analytical /
Spectroscopy},
typ = {PUB:(DE-HGF)16},
pubmed = {pmid:22976204},
UT = {WOS:000308880500003},
doi = {10.1002/rcm.6257},
url = {https://juser.fz-juelich.de/record/111945},
}