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@ARTICLE{Li:111952,
author = {Li, C.L. and Ji, R. and Schaffer, A. and Sequaris, J.M. and
Amelung, W. and Vereecken, H. and Klumpp, E.},
title = {{S}orption of a branched nonylphenol and perfluorooctanoic
acid on {Y}angtze {R}iver sediments and their model
components},
journal = {Journal of environmental monitoring},
volume = {14},
issn = {1464-0325},
address = {London},
publisher = {Royal Society of Chemistry},
reportid = {PreJuSER-111952},
pages = {2653 - 2658},
year = {2012},
note = {This study was financially supported by the National
Natural Science Foundation of China (20977043; 20777033).
Chengliang Li was supported by a scholarship from the
Deutscher Akademischer Austausch Dienst (DAAD).},
abstract = {Many metabolites of organic surfactants such as nonylphenol
(NP) and perfluorooctanoic acid (PFOA) are ubiquitously
found in the environment and are toxic if not sorbed on
soils and sediments. In this study, we quantified the
sorption of the NP isomer with the highest endocrine
activity, [4-(1-ethyl-1,3-dimethylpentyl) phenol] (NP111),
and that of PFOA on Yangtze River sediments and its model
components illite, goethite and natural organic matter. The
sorption experiments were performed with (14)C-labeled NP111
and PFOA by batch or dialysis techniques. The results showed
that the sorption isotherms of NP111 and PFOA on the
sediments were fitted well by the linear adsorption model.
The sorption of NP111 depended largely on the organic carbon
content of the sediments. The K(OC) values of NP111 ranged
from 6 × 10(3) to 1.1 × 10(4) L kg(-1) indicating that
hydrophobic interaction between NP and organic carbon is the
main mechanism of sorption. The sorption of NP111 on illite
was poor. The sorption of PFOA on the sediments was
significantly lower than that of NP111. The affinity of PFOA
to adsorb on goethite was slightly higher than on the
sediments, but was moderate on illite and negligible on a
reference natural organic matter. Principal axis component
analysis confirmed that various sediment parameters control
the binding of PFOA. This analysis grouped the respective
K(d) values to the contents of black carbon, iron oxides and
clay, and, hence, to the specific surface area of the
sediments.},
keywords = {J (WoSType)},
cin = {IBG-3},
ddc = {333.7},
cid = {I:(DE-Juel1)IBG-3-20101118},
pnm = {Terrestrische Umwelt},
pid = {G:(DE-Juel1)FUEK407},
shelfmark = {Chemistry, Analytical / Environmental Sciences},
typ = {PUB:(DE-HGF)16},
pubmed = {pmid:22892466},
UT = {WOS:000309189200012},
doi = {10.1039/c2em30394a},
url = {https://juser.fz-juelich.de/record/111952},
}