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@ARTICLE{Ibrahim:111960,
author = {Ibrahim, M. and Koglin, E.},
title = {{S}pectroscopic study of polyaniline emeraldine base:
{M}odelling approach},
journal = {Acta chimica Slovenica},
volume = {52},
issn = {1318-0207},
address = {Ljubljana},
publisher = {Drustvo},
reportid = {PreJuSER-111960},
pages = {159 - 163},
year = {2005},
note = {Record converted from VDB: 16.11.2012},
abstract = {The polymerization of aniline by Cu(II) montmorillonite was
studied using attenuated total reflection Fourier-transform
infrared (ATR-FTIR) spectroscopy. Experimental spectra were
compared with that calculated by AM1, PM3, PM5, MINDO,
Hartree-Fock, HF/6-31g(d), as well as Density Functional
Theory, BLYP/DZVP and B3LYP/6-31g(d,p). Furthermore, the
final heat of formation is studied as a function of
temperature. Results indicate that, for aniline
B3LYP/6-31G(d,p) calculated frequencies are in a good
agreement with experimental data, while HF/6-31G(d) is the
optimal in case of polyaniline. The vibrational calculations
of a four-ring unit (emeraldine base:EB) are believed to be
a good representation of the polyaniline at
Cu(II)-montmorillonite. The final heat of formation is a
function of polymerization and changed from aniline monomer
to five ring repeat unit of polyaniline structure.},
keywords = {J (WoSType)},
cin = {IBG-3},
ddc = {540},
cid = {I:(DE-Juel1)IBG-3-20101118},
pnm = {Terrestrische Umwelt},
pid = {G:(DE-Juel1)FUEK407},
shelfmark = {Chemistry, Multidisciplinary},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000229826900010},
url = {https://juser.fz-juelich.de/record/111960},
}