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@ARTICLE{Maris:112075,
author = {Maris, A. and Melandri, S. and Evangelisti, L. and
Caminati, W. and Giuliano, B. M. and Plekan, O. and Feyer,
V. and Richter, R. and Coreno, M. and Prince, K. C.},
title = {{S}oft {X}-ray photoemission spectroscopy of selected
neurotransmitters in the gas phase},
journal = {Journal of electron spectroscopy and related phenomena},
volume = {185},
issn = {0368-2048},
address = {New York, NY [u.a.]},
publisher = {Elsevier},
reportid = {PreJuSER-112075},
pages = {S244 - S251},
year = {2012},
note = {We gratefully acknowledge the assistance of our colleagues
at Elettra for providing good quality synchrotron light.
B.M.G. thanks FCT for financial support
(SFRH/BPD/44689/2008). A. Maris thanks N. Kosugi for sharing
his GSCF3 program with us and for essential discussions on
its use.},
abstract = {The valence molecular orbitals and core levels of tyramine,
tryptamine and tryptophol in the gas phase have been studied
using X-ray photoelectron spectroscopy (XPS) and theoretical
methods. The energies of the outer valence region spectrum
are found to be in agreement with previously reported He I
spectra, while new data on the inner valence molecular
orbitals are reported. The structures in the carbon,
nitrogen and oxygen core level spectra of these molecules
have been identified and assigned. These compounds are
characterised by conformers with hydrogen bonding in which
the pi systems of the phenol and indole groups act as
hydrogen acceptors, but a spectroscopic signature of this
hydrogen bond was not observed. This is in contrast with our
previous spectra of amino acids, where conformers with
specific hydrogen bonding showed strong effects in core
level spectra. We attribute the difference to the weaker
strength of the pi-hydrogen bonding. (C) 2012 Elsevier B.V.
All rights reserved.},
keywords = {J (WoSType)},
cin = {PGI-6},
ddc = {620},
cid = {I:(DE-Juel1)PGI-6-20110106},
pnm = {Grundlagen für zukünftige Informationstechnologien},
pid = {G:(DE-Juel1)FUEK412},
shelfmark = {Spectroscopy},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000308627700009},
doi = {10.1016/j.elspec.2012.06.007},
url = {https://juser.fz-juelich.de/record/112075},
}