%0 Journal Article
%A Ivanova, M.
%A Ricote, S.
%A Meulenberg, W. A.
%A Haugsrud, R.
%A Ziegner, M.
%T Effects of A- and B-site (co-)acceptor doping on the structure and proton  conductivity of LaNbO4
%J Solid state ionics
%V 213
%@ 0167-2738
%C Amsterdam [u.a.]
%I Elsevier Science
%M PreJuSER-11309
%P 45 - 52
%D 2012
%Z Record converted from VDB: 12.11.2012
%X B-site and A- and B-site co-doped lanthanum niobates, La(1-x)DA(x)Nb(1-y)DB(y)O(4-delta), where D-A stands for Ca or Ba and D-B for Ga, Ge or In (x = 0 or 0.01; y = 0.01), have been synthesized via the solid-state route. Essentially single-phase materials were obtained after 10 h at 1500 degrees C with monoclinic Fergusonite structure at room temperature. The unit cell volume increases slightly with the presence of the acceptor. The electrical conductivity of the materials, characterized as a function of the temperature from 300 degrees C to 900 degrees C under wet reducing conditions with AC impedance spectroscopy, was dominated by protons. The maximum conductivity of 4.1 . 10(-4) S . cm(-1) at 900 degrees C was obtained for La0.99Ca0.01Nb0.99Ga0.01O4-delta, which is a factor of similar to 2.5 lower than the highest conductivity reported for the A-site Ca-doped LaNbO4. Based on a semi-quantitative evaluation it was shown that the hydration of the B-site and A- and B-site co-doped LaNbO4, is slightly more exothermic and that the proton mobility has higher activation enthalpies than Ca-doped LaNbO4. This is accounted for by a stronger association between the acceptor and the proton for B-site than for A-site doping. (c) 2011 Elsevier B.V. All rights reserved.
%K J (WoSType)
%F PUB:(DE-HGF)16
%9 Journal Article
%U <Go to ISI:>//WOS:000303636900010
%R 10.1016/j.ssi.2011.06.012
%U https://juser.fz-juelich.de/record/11309