Hauptseite > Publikationsdatenbank > Effects of A- and B-site (co-)acceptor doping on the structure and proton conductivity of LaNbO4 > print |
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024 | 7 | _ | |2 DOI |a 10.1016/j.ssi.2011.06.012 |
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041 | _ | _ | |a eng |
082 | _ | _ | |a 530 |
084 | _ | _ | |2 WoS |a Chemistry, Physical |
084 | _ | _ | |2 WoS |a Physics, Condensed Matter |
100 | 1 | _ | |a Ivanova, M. |b 0 |u FZJ |0 P:(DE-Juel1)129617 |
245 | _ | _ | |a Effects of A- and B-site (co-)acceptor doping on the structure and proton conductivity of LaNbO4 |
260 | _ | _ | |a Amsterdam [u.a.] |b Elsevier Science |c 2012 |
300 | _ | _ | |a 45 - 52 |
336 | 7 | _ | |a Journal Article |0 PUB:(DE-HGF)16 |2 PUB:(DE-HGF) |
336 | 7 | _ | |a Output Types/Journal article |2 DataCite |
336 | 7 | _ | |a Journal Article |0 0 |2 EndNote |
336 | 7 | _ | |a ARTICLE |2 BibTeX |
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336 | 7 | _ | |a article |2 DRIVER |
440 | _ | 0 | |a Solid State Ionics |x 0167-2738 |0 5565 |v 213 |
500 | _ | _ | |a Record converted from VDB: 12.11.2012 |
520 | _ | _ | |a B-site and A- and B-site co-doped lanthanum niobates, La(1-x)DA(x)Nb(1-y)DB(y)O(4-delta), where D-A stands for Ca or Ba and D-B for Ga, Ge or In (x = 0 or 0.01; y = 0.01), have been synthesized via the solid-state route. Essentially single-phase materials were obtained after 10 h at 1500 degrees C with monoclinic Fergusonite structure at room temperature. The unit cell volume increases slightly with the presence of the acceptor. The electrical conductivity of the materials, characterized as a function of the temperature from 300 degrees C to 900 degrees C under wet reducing conditions with AC impedance spectroscopy, was dominated by protons. The maximum conductivity of 4.1 . 10(-4) S . cm(-1) at 900 degrees C was obtained for La0.99Ca0.01Nb0.99Ga0.01O4-delta, which is a factor of similar to 2.5 lower than the highest conductivity reported for the A-site Ca-doped LaNbO4. Based on a semi-quantitative evaluation it was shown that the hydration of the B-site and A- and B-site co-doped LaNbO4, is slightly more exothermic and that the proton mobility has higher activation enthalpies than Ca-doped LaNbO4. This is accounted for by a stronger association between the acceptor and the proton for B-site than for A-site doping. (c) 2011 Elsevier B.V. All rights reserved. |
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650 | _ | 7 | |a J |2 WoSType |
653 | 2 | 0 | |2 Author |a Proton-conducting ceramic materials |
653 | 2 | 0 | |2 Author |a Rare earth ortho-niobates |
653 | 2 | 0 | |2 Author |a Acceptor-doped lanthanum niobate |
700 | 1 | _ | |a Ricote, S. |b 1 |u FZJ |0 P:(DE-Juel1)VDB94482 |
700 | 1 | _ | |a Meulenberg, W. A. |b 2 |u FZJ |0 P:(DE-Juel1)129637 |
700 | 1 | _ | |a Haugsrud, R. |b 3 |u FZJ |0 P:(DE-Juel1)VDB94483 |
700 | 1 | _ | |a Ziegner, M. |b 4 |u FZJ |0 P:(DE-Juel1)129815 |
773 | _ | _ | |a 10.1016/j.ssi.2011.06.012 |g Vol. 213, p. 45 - 52 |p 45 - 52 |q 213<45 - 52 |0 PERI:(DE-600)1500750-9 |t Solid state ionics |v 213 |y 2012 |x 0167-2738 |
856 | 7 | _ | |u http://dx.doi.org/10.1016/j.ssi.2011.06.012 |
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913 | 2 | _ | |a DE-HGF |b Forschungsbereich Energie |l Energieeffizienz, Materialien und Ressourcen |1 G:(DE-HGF)POF3-110 |0 G:(DE-HGF)POF3-113 |2 G:(DE-HGF)POF3-100 |v Methods and Concepts for Material Development |x 0 |
914 | 1 | _ | |y 2012 |
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