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024 7 _ |2 DOI
|a 10.1016/j.ssi.2011.06.012
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082 _ _ |a 530
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|a Chemistry, Physical
084 _ _ |2 WoS
|a Physics, Condensed Matter
100 1 _ |a Ivanova, M.
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245 _ _ |a Effects of A- and B-site (co-)acceptor doping on the structure and proton conductivity of LaNbO4
260 _ _ |a Amsterdam [u.a.]
|b Elsevier Science
|c 2012
300 _ _ |a 45 - 52
336 7 _ |a Journal Article
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440 _ 0 |a Solid State Ionics
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500 _ _ |a Record converted from VDB: 12.11.2012
520 _ _ |a B-site and A- and B-site co-doped lanthanum niobates, La(1-x)DA(x)Nb(1-y)DB(y)O(4-delta), where D-A stands for Ca or Ba and D-B for Ga, Ge or In (x = 0 or 0.01; y = 0.01), have been synthesized via the solid-state route. Essentially single-phase materials were obtained after 10 h at 1500 degrees C with monoclinic Fergusonite structure at room temperature. The unit cell volume increases slightly with the presence of the acceptor. The electrical conductivity of the materials, characterized as a function of the temperature from 300 degrees C to 900 degrees C under wet reducing conditions with AC impedance spectroscopy, was dominated by protons. The maximum conductivity of 4.1 . 10(-4) S . cm(-1) at 900 degrees C was obtained for La0.99Ca0.01Nb0.99Ga0.01O4-delta, which is a factor of similar to 2.5 lower than the highest conductivity reported for the A-site Ca-doped LaNbO4. Based on a semi-quantitative evaluation it was shown that the hydration of the B-site and A- and B-site co-doped LaNbO4, is slightly more exothermic and that the proton mobility has higher activation enthalpies than Ca-doped LaNbO4. This is accounted for by a stronger association between the acceptor and the proton for B-site than for A-site doping. (c) 2011 Elsevier B.V. All rights reserved.
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|a Proton-conducting ceramic materials
653 2 0 |2 Author
|a Rare earth ortho-niobates
653 2 0 |2 Author
|a Acceptor-doped lanthanum niobate
700 1 _ |a Ricote, S.
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700 1 _ |a Meulenberg, W. A.
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700 1 _ |a Haugsrud, R.
|b 3
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|0 P:(DE-Juel1)VDB94483
700 1 _ |a Ziegner, M.
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773 _ _ |a 10.1016/j.ssi.2011.06.012
|g Vol. 213, p. 45 - 52
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|t Solid state ionics
|v 213
|y 2012
|x 0167-2738
856 7 _ |u http://dx.doi.org/10.1016/j.ssi.2011.06.012
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