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@ARTICLE{Zhang:11861,
      author       = {Zhang, J. and Séquaris, J.-M. and Narres, H.-D. and
                      Vereecken, H. and Klumpp, E.},
      title        = {{P}yrene and {P}henanthrene {S}orption to {M}odel and
                      {N}atural {G}eosorbents in {S}ingle- and {B}inary-{S}olute
                      {S}ystems},
      journal      = {Environmental Science $\&$ Technology},
      volume       = {44},
      issn         = {0013-936X},
      address      = {Columbus, Ohio},
      publisher    = {American Chemical Society},
      reportid     = {PreJuSER-11861},
      pages        = {8102 - 8107},
      year         = {2010},
      note         = {Record converted from VDB: 12.11.2012},
      abstract     = {Sorption of pyrene and phenanthrene to model (illite and
                      charcoal) and natural (Yangtze sediment) geosorbents were
                      investigated by batch techniques using fluorescence
                      spectroscopy. A higher adsorption of phenanthrene was
                      observed with all sorbents, which is related to the better
                      accessibility of smaller molecules to micropores in the
                      molecular sieve sorbents. In addition, pyrene sorption in
                      binary-solute systems with a constant initial concentration
                      of phenanthrene (0.1 μmol L(-1) or 2 μmol L(-1)) was
                      studied. A 0.1 μmol L(-1) concentration of phenanthrene
                      causes no competitive effect on the pyrene sorption. A 2
                      μmol L(-1) concentration of phenanthrene significantly
                      suppresses the sorption of pyrene, especially in the low
                      concentration range; nonlinearity of the pyrene sorption
                      isotherms thus decreases. The competitive effect of 2 μmol
                      L(-1) phenanthrene on the pyrene sorption is overestimated
                      by the ideal adsorbed solution theory (IAST) using the
                      fitted single sorption results of both solutes. An
                      adjustment of the IAST application by taking into account
                      the molecular sieve effect is proposed, which notably
                      improves the IAST prediction for the competitive effect.},
      keywords     = {Absorption / Adsorption / Charcoal: chemistry / Geologic
                      Sediments: chemistry / Minerals: chemistry / Models,
                      Chemical / Phenanthrenes: chemistry / Pyrenes: chemistry /
                      Solutions / Spectrometry, Fluorescence / Minerals (NLM
                      Chemicals) / Phenanthrenes (NLM Chemicals) / Pyrenes (NLM
                      Chemicals) / Solutions (NLM Chemicals) / illite (NLM
                      Chemicals) / pyrene (NLM Chemicals) / Charcoal (NLM
                      Chemicals) / phenanthrene (NLM Chemicals) / J (WoSType)},
      cin          = {ICG-4 / JARA-HPC},
      ddc          = {050},
      cid          = {I:(DE-Juel1)VDB793 / $I:(DE-82)080012_20140620$},
      pnm          = {Terrestrische Umwelt},
      pid          = {G:(DE-Juel1)FUEK407},
      shelfmark    = {Engineering, Environmental / Environmental Sciences},
      typ          = {PUB:(DE-HGF)16},
      pubmed       = {pmid:20886848},
      UT           = {WOS:000283484000023},
      doi          = {10.1021/es1010847},
      url          = {https://juser.fz-juelich.de/record/11861},
}