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@ARTICLE{Wdowik:11953,
author = {Wdowik, U.D. and Parlinski, K. and Chatterji, T. and Rols,
S. and Schober, H.},
title = {{L}attice dynamics of rhenium trioxide from the
quasiharmonic approximation},
journal = {Physical review / B},
volume = {82},
number = {10},
issn = {1098-0121},
address = {College Park, Md.},
publisher = {APS},
reportid = {PreJuSER-11953},
pages = {104301},
year = {2010},
note = {Interdisciplinary Modeling Center ICM, Warsaw University,
Poland is acknowledged for providing the computer facilities
to support part of the present calculations under Grant No.
G28-12.},
abstract = {The quasiharmonic theory is applied to study the lattice
dynamics and thermal properties of rhenium trioxide, a
material exhibiting the negative thermal-expansion
phenomenon. Phonons are calculated at several external
pressures. The pressure dependence of the M, R, and
zone-center phonon modes is analyzed. Relying on the
Gruneisen formalism an influence of temperature on the M
phonon mode is investigated. The calculated free energy of
the system provides predictions for the temperature
dependence of such quantities as equilibrium volume and
crystal thermal expansivity. The mean-squared vibrations of
rhenium-trioxide atoms are investigated versus temperature
and pressure. Results of the calculations indicate a
softening of the M and R phonons with pressure and a large
negative Gruneisen constants for these modes. A decrease in
the crystal volume is observed up to 170 K. The
thermal-expansion coefficient shows a minimum in the
vicinity of 100 K which corresponds to a minimum of the
anisotropy in the oxygen thermal vibrations perpendicular to
the Re-O bond and along the bond. Anisotropy in the oxygen
Debye-Waller factors follows from the anisotropy of the
force constants at the oxygen site. Inelastic
neutron-scattering measurements performed at room
temperature are reported together with the generalized
phonon densities of states. A comparison between present
calculations and the experimental data as well as other
theoretical studies is provided.},
keywords = {J (WoSType)},
cin = {IFF-5 / IFF-4 / Jülich Centre for Neutron Science JCNS
(JCNS) ; JCNS},
ddc = {530},
cid = {I:(DE-Juel1)VDB785 / I:(DE-Juel1)VDB784 /
I:(DE-Juel1)JCNS-20121112},
pnm = {BioSoft: Makromolekulare Systeme und biologische
Informationsverarbeitung / Großgeräte für die Forschung
mit Photonen, Neutronen und Ionen (PNI)},
pid = {G:(DE-Juel1)FUEK505 / G:(DE-Juel1)FUEK415},
shelfmark = {Physics, Condensed Matter},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000281720100003},
doi = {10.1103/PhysRevB.82.104301},
url = {https://juser.fz-juelich.de/record/11953},
}