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@ARTICLE{Koepke:12494,
author = {Koepke, P. and Garhammer, M. and Hess, M. and Roeth, E.-P.},
title = {{NO}2 photolysis frequencies in street canyons},
journal = {Atmospheric chemistry and physics},
volume = {10},
issn = {1680-7316},
address = {Katlenburg-Lindau},
publisher = {EGU},
reportid = {PreJuSER-12494},
pages = {7457 - 7466},
year = {2010},
note = {Financial support by the German Umweltbundesamt under
UFOPLAN Grant 370942207 is gratefully acknowledged.},
abstract = {Photolysis frequencies for NO2 are modeled for the
conditions in urban streets, which are taken into account as
canyons with variable height and width. The effect of a
street canyon is presented with absolute values and as a
ratio RJ of the photolysis frequency within the street
compared to that with free horizon. This allows further use
of the existing photolysis parameterizations. Values are
presented for variable solar elevation and azimuth angles,
varying atmospheric conditions and different street
properties. The NO2 photolysis frequency in a street depends
strongly on the relative width of the street and its
orientation towards the sun. Averaged over atmospheric
conditions and street orientation, the NO2 photolysis
frequency is reduced in comparison with the values for free
horizon: to less than $20\%$ for narrow skyscraper streets,
to about $40\%$ for typical urban streets, and only to about
$80\%$ for garden streets. A parameterization with the
global solar irradiance is given for the averaged RJ
values.},
keywords = {J (WoSType)},
cin = {IEK-7},
ddc = {550},
cid = {I:(DE-Juel1)IEK-7-20101013},
pnm = {Atmosphäre und Klima},
pid = {G:(DE-Juel1)FUEK491},
shelfmark = {Meteorology $\&$ Atmospheric Sciences},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000280847700032},
doi = {10.5194/acpd-10-12827-2010},
url = {https://juser.fz-juelich.de/record/12494},
}