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000012977 084__ $$2WoS$$aChemistry, Multidisciplinary
000012977 084__ $$2WoS$$aChemistry, Physical
000012977 084__ $$2WoS$$aMaterials Science, Multidisciplinary
000012977 1001_ $$0P:(DE-HGF)0$$aFrielinghaus, X.$$b0
000012977 245__ $$aConfined Polymer Dynamics on Clay Platelets
000012977 260__ $$aWashington, DC$$bACS Publ.$$c2010
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000012977 520__ $$aThe structure and dynamics of poly(ethylene oxide) adsorbed on dispersed clay platelets are investigated by small-angle neutron scattering and neutron spin-echo spectroscopy. The intermediate scattering function has a mobile contribution described by the Zimm theory and an immobile contribution that is constant within the time window. The immobile fraction as a function of the scattering vector Q is described by a Lorentz function, from which a localization length is determined. The relaxation rates grow with polymer concentration in agreement with dielectric measurements but contrary to pure polymer gels.
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000012977 7001_ $$0P:(DE-Juel1)VDB60009$$aBrodeck, M.$$b1$$uFZJ
000012977 7001_ $$0P:(DE-Juel1)130718$$aHolderer, O.$$b2$$uFZJ
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000012977 8567_ $$uhttp://dx.doi.org/10.1021/la102667k
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000012977 9132_ $$0G:(DE-HGF)POF3-623$$1G:(DE-HGF)POF3-620$$2G:(DE-HGF)POF3-600$$aDE-HGF$$bForschungsbereich Materie$$lIn-house research on the structure, dynamics and function of matter$$vNeutrons for Research on Condensed Matter$$x0
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