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@ARTICLE{Dhont:13065,
author = {Dhont, J.K.G. and Kang, K. and Lettinga, M.P. and Briels,
W.J.},
title = {{S}hear-banding instabilities},
journal = {Korea-Australia rheology journal},
volume = {22},
issn = {1226-119X},
address = {Berlin},
publisher = {Springer},
reportid = {PreJuSER-13065},
pages = {291 - 308},
year = {2010},
note = {Record converted from VDB: 12.11.2012},
abstract = {Gradient-banding and vorticity-banding instabilities, as
well as a shear-induced instability due to shear-gradient
induced mass transport will be discussed. Various scenarios
that underly these instabilities are addressed and simple
constitutive relations that allow for a (semi-) quantitative
analysis are proposed. A relatively simple constitutive
equation that has been proposed some time ago is reviewed,
which captures a number of the experimentally observed
gradient-banding phenomena. This constitutive equation is
based on the usual formal expansion of the stress tensor
with respect to gradients in the flow velocity, but now
including the second order term. The second order term is
necessary to describe the relatively large spatial gradients
within the interface between the two bands. The resulting
simple constitutive equation is shown to give rise to
stationary gradient-banded states, where the shear rates
within the bands are constant, it describes stress selection
under controlled rate conditions and explains why banding
can not occur under controlled stress conditions. The simple
constitutive equation does not include coupling to
concentration, which may give rise to banding also under
controlled stress conditions. Two examples of mechanisms
that lead to the strong shear thinning that is necessary for
gradient banding are discussed: (i) transient forces due to
entanglements in polymer systems, and (ii) critical slowing
down. The latter mechanism is shown to be important for a
worm-like micellar system. The mechanism that leads to
vorticity banding is still under debate. Vorticity banding
of fd-virus suspensions within the two-phase
isotropic-nematic coexistence will be discussed. Experiments
on the kinetics of banding and particle-tracking experiments
lead to a recently proposed mechanism for the
vorticity-banding instability, where the instability is
identified as an elastic instability similar to the
polymer-Weissenberg effect. The role of polymer chains in
the classic Weissenberg effect is now played by
inhomogeneities formed during the initial stages of phase
separation. For other systems than fd-virus suspensions that
exhibit vorticity banding, the inhomogeneities general have
a different origin, like in weakly aggregated colloids and
worm-like micellar systems where the inhomogeneities are the
colloidal aggregates and the worms, respectively. An
instability that has been discovered some time ago, which is
an instability due to shear-gradient induced mass transport
is also discussed. The coupling between shear-gradients and
mass transport has been formally introduced through a
shear-rate dependent chemical potential, of which the
microscopic origin was not explained. It will be shown that
the microscopic origin of this coupling is related to the
shear-induced distortion of the pair-correlation function.
Contrary to the stationary gradient-banded and
vorticity-banded state, it is not yet known what the
stationary state is when this shear-concentration-coupling
instability occurs.},
keywords = {J (WoSType)},
cin = {ICS-3},
ddc = {530},
cid = {I:(DE-Juel1)ICS-3-20110106},
pnm = {BioSoft: Makromolekulare Systeme und biologische
Informationsverarbeitung (FUEK505) / 450 - BioSoft
(POF2-400)},
pid = {G:(DE-Juel1)FUEK505 / G:(DE-HGF)POF2-450},
shelfmark = {Mechanics / Polymer Science},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000285982000007},
url = {https://juser.fz-juelich.de/record/13065},
}