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000132944 1001_ $$0P:(DE-Juel1)130777$$aKrutyeva, Margarita$$b0$$eCorresponding author$$ufzj
000132944 245__ $$aEffect of Nanoconfinement on Polymer Dynamics: Surface Layers and Interphases
000132944 260__ $$aCollege Park, Md.$$bAPS$$c2013
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000132944 520__ $$aWe present neutron spin echo experiments that address the much debated topic of dynamic phenomena in polymer melts that are induced by interacting with a confining surface. We find an anchored surface layer that internally is highly mobile and not glassy as heavily promoted in the literature. The polymer dynamics in confinement is, rather, determined by two phases, one fully equal to the bulk polymer and another that is partly anchored at the surface. By strong topological interaction, this phase confines further chains with no direct contact to the surface. These form the often invoked interphase, where the full chain relaxation is impeded through the interaction with the anchored chains.
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000132944 65027 $$0V:(DE-MLZ)SciArea-210$$2V:(DE-HGF)$$aSoft Condensed Matter$$x0
000132944 65017 $$0V:(DE-MLZ)GC-1602-2016$$2V:(DE-HGF)$$aPolymers, Soft Nano Particles and  Proteins$$x2
000132944 65017 $$0V:(DE-MLZ)GC-150-1$$2V:(DE-HGF)$$aKey Technologies$$x1
000132944 65017 $$0V:(DE-MLZ)GC-150$$2V:(DE-HGF)$$aNano Science and Technology$$x0
000132944 693__ $$0EXP:(DE-MLZ)J-NSE-20140101$$1EXP:(DE-MLZ)FRMII-20140101$$5EXP:(DE-MLZ)J-NSE-20140101$$6EXP:(DE-MLZ)NL2ao-20140101$$aForschungs-Neutronenquelle Heinz Maier-Leibnitz$$eJ-NSE: Neutron spin-echo spectrometer$$fNL2ao$$x0
000132944 693__ $$0EXP:(DE-MLZ)KWS2-20140101$$1EXP:(DE-MLZ)FRMII-20140101$$5EXP:(DE-MLZ)KWS2-20140101$$6EXP:(DE-MLZ)NL3ao-20140101$$aForschungs-Neutronenquelle Heinz Maier-Leibnitz$$eKWS-2: Small angle scattering diffractometer$$fNL3ao$$x1
000132944 7001_ $$0P:(DE-Juel1)131040$$aWischnewski, Andreas$$b1$$ufzj
000132944 7001_ $$0P:(DE-Juel1)130849$$aMonkenbusch, Michael$$b2$$ufzj
000132944 7001_ $$0P:(DE-Juel1)131036$$aWillner, Lutz$$b3$$ufzj
000132944 7001_ $$0P:(DE-HGF)0$$aMaiz, J.$$b4
000132944 7001_ $$0P:(DE-Juel1)VDB89820$$aMijangos, C.$$b5
000132944 7001_ $$0P:(DE-Juel1)VDB4257$$aArbe, A.$$b6
000132944 7001_ $$0P:(DE-Juel1)VDB4258$$aColmenero, J.$$b7
000132944 7001_ $$0P:(DE-Juel1)130905$$aRadulescu, Aurel$$b8$$ufzj
000132944 7001_ $$0P:(DE-Juel1)130718$$aHolderer, Olaf$$b9$$ufzj
000132944 7001_ $$0P:(DE-Juel1)130872$$aOhl, Michael$$b10$$ufzj
000132944 7001_ $$0P:(DE-Juel1)130917$$aRichter, Dieter$$b11$$ufzj
000132944 773__ $$0PERI:(DE-600)1472655-5$$a10.1103/PhysRevLett.110.108303$$p108303$$tPhysical review letters$$v110$$x0031-9007
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