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@ARTICLE{Krutyeva:132944,
author = {Krutyeva, Margarita and Wischnewski, Andreas and
Monkenbusch, Michael and Willner, Lutz and Maiz, J. and
Mijangos, C. and Arbe, A. and Colmenero, J. and Radulescu,
Aurel and Holderer, Olaf and Ohl, Michael and Richter,
Dieter},
title = {{E}ffect of {N}anoconfinement on {P}olymer {D}ynamics:
{S}urface {L}ayers and {I}nterphases},
journal = {Physical review letters},
volume = {110},
issn = {0031-9007},
address = {College Park, Md.},
publisher = {APS},
reportid = {FZJ-2013-01513},
pages = {108303},
year = {2013},
abstract = {We present neutron spin echo experiments that address the
much debated topic of dynamic phenomena in polymer melts
that are induced by interacting with a confining surface. We
find an anchored surface layer that internally is highly
mobile and not glassy as heavily promoted in the literature.
The polymer dynamics in confinement is, rather, determined
by two phases, one fully equal to the bulk polymer and
another that is partly anchored at the surface. By strong
topological interaction, this phase confines further chains
with no direct contact to the surface. These form the often
invoked interphase, where the full chain relaxation is
impeded through the interaction with the anchored chains.},
cin = {JCNS-1 / ICS-1 / JCNS (München) ; Jülich Centre for
Neutron Science JCNS (München) ; JCNS-FRM-II / JCNS-SNS},
ddc = {550},
cid = {I:(DE-Juel1)JCNS-1-20110106 / I:(DE-Juel1)ICS-1-20110106 /
I:(DE-Juel1)JCNS-FRM-II-20110218 /
I:(DE-Juel1)JCNS-SNS-20110128},
pnm = {451 - Soft Matter Composites (POF2-451)},
pid = {G:(DE-HGF)POF2-451},
experiment = {EXP:(DE-MLZ)J-NSE-20140101 / EXP:(DE-MLZ)KWS2-20140101},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000315744700028},
doi = {10.1103/PhysRevLett.110.108303},
url = {https://juser.fz-juelich.de/record/132944},
}