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@INPROCEEDINGS{Lettinga:133529,
author = {Lettinga, Pavlik and Holmqvist, Peter and Kleshchanok, D.
and Ballesta, Pierre and Rogers, S.A. and Kohlbrecher, J.
and Struth, B.},
title = {{I}n situ large amplitude oscillatory shear ({LAOS})
experiments on rod-like viruses and colloidal platelets},
school = {TU Berlin},
reportid = {FZJ-2013-01963},
year = {2012},
abstract = {Highly anisotropic particles are by nature susceptible to
external fields. In particular shear forces can cause a
pronounced shear thinning, where a highly viscous unordered
system is sheared into a low viscous ordered system. This
makes shear thinning behavior both fundamentally and
practically interesting. The rheological and structural
responses of the system at the onset of shear thinning can
be conveniently studied by large amplitude oscillatory shear
(LAOS) in combination with in situ scattering techniques.
Here we study two systems: 1) dispersions of rod-like (fd)
viruses approaching the isotropic - nematic transition in
combination with time-resolved small-angle neutron
scattering; 2) dispersions of gibbsite platelets around the
nematic phase in combination with time-resolved small-angle
X-ray scattering. Viewing the responses as indicating a
sequence of physical processes, we identify, for the
rod-dispersions, a region of purely elastic response
accompanied by an increase in the orientational ordering. By
yielding this is followed in sequence by a region of
fluid-like behavior at an almost constant ordering. The
platelet dispersions display, for a broad range of
frequencies, a transition from singlet feature in the
scattering at small strain amplitude to a doublet at large
strain amplitude. This suggests the existence of a critical
strain for reorienting the platelets, which is not reflected
in the bulk rheology.},
month = {Mar},
date = {2012-03-25},
organization = {76th Annual Meeting of the DPG and DPG
Spring Meeting, Berlin (Germany), 25
Mar 2012 - 30 Mar 2012},
subtyp = {Other},
cin = {ICS-3},
cid = {I:(DE-Juel1)ICS-3-20110106},
pnm = {451 - Soft Matter Composites (POF2-451)},
pid = {G:(DE-HGF)POF2-451},
typ = {PUB:(DE-HGF)6},
url = {https://juser.fz-juelich.de/record/133529},
}