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@ARTICLE{Eichel:134817,
author = {Eichel, Rüdiger-A. and Erünal, Ebru and Jakes, Peter and
Körbel, Sabine and Elsässer, Christian and Kungl, Hans and
Acker, $Jéro^me$ and Hoffmann, Michael J.},
title = {{I}nteractions of defect complexes and domain walls in
{C}u{O}-doped ferroelectric ({K},{N}a){N}b{O}3123},
journal = {Applied physics letters},
volume = {102},
number = {24},
issn = {0003-6951},
address = {Melville, NY},
publisher = {American Institute of Physics},
reportid = {FZJ-2013-02892},
pages = {242908 -},
year = {2013},
abstract = {“Lead-free” piezoelectric sodium potassium niobate has
been studied with respect to its defect structure when
doping with CuO. The results indicate that two kinds of
mutually compensating charged defect complexes are formed,
(Cu′′′Nb−VO••)′ and
(VO••−Cu′′′Nb−VO••)•. Concerning the
interplay of these defect complexes with the piezoelectric
materials properties, the trimeric
(VO••−Cu′′′Nb−VO••)• defect complex
primarily has an elastic dipole moment and thus is proposed
to impact the electromechanical properties, whereas the
dimeric (Cu′′′Nb−VO••)′ defect possesses an
electric dipole moment in addition to an elastic distortion.
Both types of defect complexes can impede domain-wall motion
and may contribute to ferroelectric “hardening.”},
cin = {IEK-9},
ddc = {530},
cid = {I:(DE-Juel1)IEK-9-20110218},
pnm = {152 - Renewable Energies (POF2-152) / 123 - Fuel Cells
(POF2-123)},
pid = {G:(DE-HGF)POF2-152 / G:(DE-HGF)POF2-123},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000320962400080},
doi = {10.1063/1.4811268},
url = {https://juser.fz-juelich.de/record/134817},
}