001 | 135215 | ||
005 | 20210129211817.0 | ||
024 | 7 | _ | |a 10.1063/1.4813098 |2 doi |
024 | 7 | _ | |a 0021-8979 |2 ISSN |
024 | 7 | _ | |a 1089-7550 |2 ISSN |
024 | 7 | _ | |a WOS:000322202700050 |2 WOS |
024 | 7 | _ | |a 2128/16814 |2 Handle |
037 | _ | _ | |a FZJ-2013-03175 |
082 | _ | _ | |a 530 |
100 | 1 | _ | |a Sagarna, L. |0 P:(DE-HGF)0 |b 0 |e Corresponding author |
245 | _ | _ | |a Structure and thermoelectric properties of EuTi(O,N)3 ± δ |
260 | _ | _ | |a Melville, NY |c 2013 |b American Institute of Physics |
336 | 7 | _ | |a article |2 DRIVER |
336 | 7 | _ | |a Output Types/Journal article |2 DataCite |
336 | 7 | _ | |a Journal Article |b journal |m journal |0 PUB:(DE-HGF)16 |s 1396512527_14486 |2 PUB:(DE-HGF) |
336 | 7 | _ | |a ARTICLE |2 BibTeX |
336 | 7 | _ | |a JOURNAL_ARTICLE |2 ORCID |
336 | 7 | _ | |a Journal Article |0 0 |2 EndNote |
500 | _ | _ | |3 POF3_Assignment on 2016-02-29 |
520 | _ | _ | |a After partial substitution of nitrogen for oxygen in EuTiO3, the crystal structure, thermoelectric properties, morphology, and electronic structure of the products were analyzed and compared with pristine EuTiO3. The space group of EuTi(O,N)3 ± δ was orthorhombic Pnma due to the tilt and rotation of the anion octahedra, compared to cubic Pm3¯m of EuTiO3 (at room temperature). The thermoelectric properties of oxynitride polycrystalline bodies sintered in three different ways were investigated in the temperature range of 300 K < T < 950 K. The Seebeck coefficients (S) of the oxynitrides were lower compared with the oxide, and the electrical resistivities (ρ) were increased about one order of magnitude. The activation energies (E A) indicated a larger band gap of EuTi(O,N)3 ± δ when compared to the pristine EuTiO3 (∼1.3 eV compared to 0.98 eV). A morphological characterization by transmission electron microscopy and scanning electron microscopy illustrated intrinsic nanopores within the individual particles and weak grain-interconnections indicating poor intergrain electron transport. Ab initio calculations of the electronic structures confirmed a larger band gap of the distorted crystal structure of the oxynitride and showed a decrease of the density of states at the Fermi level, explaining the reduction of the measured S. |
536 | _ | _ | |a 421 - Frontiers of charge based Electronics (POF2-421) |0 G:(DE-HGF)POF2-421 |c POF2-421 |f POF II |x 0 |
588 | _ | _ | |a Dataset connected to CrossRef, juser.fz-juelich.de |
700 | 1 | _ | |a Rushchanskii, K. Z. |0 P:(DE-Juel1)VDB103228 |b 1 |
700 | 1 | _ | |a Maegli, A. |0 P:(DE-HGF)0 |b 2 |
700 | 1 | _ | |a Yoon, S. |0 P:(DE-Juel1)VDB88648 |b 3 |
700 | 1 | _ | |a Populoh, S. |0 P:(DE-HGF)0 |b 4 |
700 | 1 | _ | |a Shkabko, A. |0 P:(DE-Juel1)145072 |b 5 |u fzj |
700 | 1 | _ | |a Pokrant, S. |0 P:(DE-HGF)0 |b 6 |
700 | 1 | _ | |a Ležaić, M. |0 P:(DE-Juel1)130799 |b 7 |u fzj |
700 | 1 | _ | |a Waser, R. |0 P:(DE-Juel1)131022 |b 8 |u fzj |
700 | 1 | _ | |a Weidenkaff, A. |0 P:(DE-Juel1)VDB85462 |b 9 |
773 | _ | _ | |a 10.1063/1.4813098 |g Vol. 114, no. 3, p. 033701 - |0 PERI:(DE-600)1476463-5 |n 3 |p 033701 - |t Journal of applied physics |v 114 |y 2013 |x 0021-8979 |
856 | 4 | _ | |u https://juser.fz-juelich.de/record/135215/files/FZJ-2013-03175.pdf |y OpenAccess |z Published final document. |
909 | C | O | |o oai:juser.fz-juelich.de:135215 |p openaire |p open_access |p VDB |p driver |p dnbdelivery |
910 | 1 | _ | |a Forschungszentrum Jülich GmbH |0 I:(DE-588b)5008462-8 |k FZJ |b 5 |6 P:(DE-Juel1)145072 |
910 | 1 | _ | |a Forschungszentrum Jülich GmbH |0 I:(DE-588b)5008462-8 |k FZJ |b 7 |6 P:(DE-Juel1)130799 |
910 | 1 | _ | |a Forschungszentrum Jülich GmbH |0 I:(DE-588b)5008462-8 |k FZJ |b 8 |6 P:(DE-Juel1)131022 |
913 | 2 | _ | |a DE-HGF |b Key Technologies |l Future Information Technology - Fundamentals, Novel Concepts and Energy Efficiency (FIT) |1 G:(DE-HGF)POF3-520 |0 G:(DE-HGF)POF3-529H |2 G:(DE-HGF)POF3-500 |v Addenda |x 0 |
913 | 1 | _ | |a DE-HGF |b Schlüsseltechnologien |1 G:(DE-HGF)POF2-420 |0 G:(DE-HGF)POF2-421 |2 G:(DE-HGF)POF2-400 |v Frontiers of charge based Electronics |x 0 |4 G:(DE-HGF)POF |3 G:(DE-HGF)POF2 |l Grundlagen zukünftiger Informationstechnologien |
914 | 1 | _ | |y 2013 |
915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)0150 |2 StatID |b Web of Science Core Collection |
915 | _ | _ | |a JCR |0 StatID:(DE-HGF)0100 |2 StatID |
915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)0200 |2 StatID |b SCOPUS |
915 | _ | _ | |a WoS |0 StatID:(DE-HGF)0110 |2 StatID |b Science Citation Index |
915 | _ | _ | |a WoS |0 StatID:(DE-HGF)0111 |2 StatID |b Science Citation Index Expanded |
915 | _ | _ | |a OpenAccess |0 StatID:(DE-HGF)0510 |2 StatID |
915 | _ | _ | |a JCR/ISI refereed |0 StatID:(DE-HGF)0010 |2 StatID |
915 | _ | _ | |a Allianz-Lizenz / DFG |0 StatID:(DE-HGF)0400 |2 StatID |
915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)0300 |2 StatID |b Medline |
915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)1020 |2 StatID |b Current Contents - Social and Behavioral Sciences |
915 | _ | _ | |a Nationallizenz |0 StatID:(DE-HGF)0420 |2 StatID |
915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)0199 |2 StatID |b Thomson Reuters Master Journal List |
920 | 1 | _ | |0 I:(DE-Juel1)PGI-1-20110106 |k PGI-1 |l Quanten-Theorie der Materialien |x 0 |
920 | 1 | _ | |0 I:(DE-Juel1)PGI-7-20110106 |k PGI-7 |l Elektronische Materialien |x 1 |
920 | 1 | _ | |0 I:(DE-82)080009_20140620 |k JARA-FIT |l JARA-FIT |x 2 |
980 | _ | _ | |a journal |
980 | _ | _ | |a VDB |
980 | _ | _ | |a UNRESTRICTED |
980 | _ | _ | |a I:(DE-Juel1)PGI-1-20110106 |
980 | _ | _ | |a I:(DE-Juel1)PGI-7-20110106 |
980 | _ | _ | |a I:(DE-82)080009_20140620 |
980 | 1 | _ | |a FullTexts |
981 | _ | _ | |a I:(DE-Juel1)PGI-7-20110106 |
Library | Collection | CLSMajor | CLSMinor | Language | Author |
---|