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@TECHREPORT{Poppe:136107,
      author       = {Poppe, Dirk and Zimmermann, Jörg and Institut für
                      Atmosphärische Chemie (Jülich, 3) - ICG3},
      title        = {{A} supplement for the {RADM}2 chemical mechanism: the
                      photooxidation of isoprene},
      volume       = {2938},
      number       = {Juel-2938},
      address      = {Jülich},
      publisher    = {Forschungszentrum Jülich GmbH Zentralbibliothek, Verlag},
      reportid     = {PreJuSER-136107, Juel-2938},
      series       = {Berichte des Forschungszentrums Jülich},
      pages        = {38 S., Anh.},
      year         = {1994},
      note         = {Record converted from JUWEL: 18.07.2013},
      abstract     = {During recent years the importance of isoprene as a
                      reactive biogenic hydrocarbon has been recognized. Since
                      isoprene is poorly represented in RADM2 we have developed an
                      extension by a comprehensive isoprene chemistry. This
                      detailed mechanism (RADM-E) leads to the same results as
                      RADM2 for vanishing concentration of isoprene. The main
                      consequences are the enhanced production of organic nitrates
                      in the course of the isoprene oxidation and the improved
                      conservation of carbon compounds in RADM-E. The balanced
                      C-budget brings about higher concentrations of peroxy
                      radicals and organic peroxides. The formation of organic
                      nitrates leads to smaller amounts of other reactive
                      N-compounds, affecting directly NO" HNO., and PAN, and
                      indirectly uo H 0 '" J~ n Xl 2 2' Qi10 v S' Since RADM-E
                      includes 34 new species and i 12 additional reactions it is
                      not suitable for use in three dimensional transport and
                      chemistry calculation. Therefore a condensed version
                      (RADM-C) was developed with only 8 new species and 19
                      additional reactions. RADM-C gives approximately the same
                      results as RADM-E, if [NO,] > 0.1 ppb. RADM-E is also
                      compared with the chemical mechanism of Lurmann et al.
                      (1986), which is widely used and includes the chemistry of
                      isoprene in a different manner. in four scenarios, covering
                      typical situations with high impact of isoprene, the
                      chemical mechanisms RADM2 and RADM-C are compared, utilizing
                      a simple 2-boxmodel. Differences of concentrations can
                      exceed 10 percent for 0. and a factor of 2 for HO"
                      peroxides, NO" PAN, and HN03• Carbonyl compounds show even
                      higher differences.},
      cin          = {ICG-3 / ICG-3},
      cid          = {I:(DE-Juel1)ICG-3-20090406 / I:(DE-Juel1)VDB142},
      shelfmark    = {UMB - Atmospheric chemistry},
      typ          = {PUB:(DE-HGF)29},
      url          = {https://juser.fz-juelich.de/record/136107},
}