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Forschungszentrum Jülich Institut für Festkörperforschung
Isotropic/ Nematic Pre-transition of Polybutadiene-b-poly(ethyleneoxide) induced by a wall
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Peter Lang We have investigated the influence of the flat interface between
a silicon single crystal and aqueous polybutadiene-b-poly(ethyleneoxide)
solutions on the solutions' isotropic to nematic phase transition
(I/N). An I/N pre-transition is induced by the wall at volume fractions
of the polymer which are about 15% smaller than required for the
phase transition in the bulk. Contrary to theoretical predictions
for hard rod fluids and semi-flexible polymer systems this pre-transition
is not followed by complete wetting of the interface by the nematic
phase upon further increase of the polymer volume fraction. |
