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Forschungszentrum Jülich Institut für Festkörperforschung
Shear-Induced Distortion of the Microstructure in near-Critical Colloids
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H. Wang, M. P. Lettinga We discuss small angle light scattering (SALS) by a near-critical
colloidal system under shear flow. A newly developed optical shear
cell allows for accurate SALS measurements under shear flow, and
thus enables to di-rectly compare the experimental structurefactor
with the theoretical predictions [l,2]. The structurefactor relates
to macroscopic quantities, such as the critical divergence of the
shear-viscosity, the non-analytic dependence of turbidity on shear-rate
and the critical behavior of flow induced dichroism. Contrary to
the theoretical predic-tion, we find experimentally a significant
distortion of the structurefactor at small scattering angles in
directions perpendicular to the flow direction. We show that shear-induced
distortion of short-ranged correlations (once was neglected in an
earlier theory [1,2]) are responsible for the observed distortion
of long-ranged correlations per-pendicular to the flow direction.
The importance of dis-tortions on small scale for the distortion
on large scale critical microstructure partly destroys universality
as it is known for the critical behaviour of systems in the absence
of shear flow, in the sense that critical microstructure under shear
flow depends on short-ranged correlations, and thereby on the details
of the pair-interaction poten-tial. The integrated quantities mentioned
above (such as the viscosity) are not very sensitive to distortions
in directions perpendicular to the flow direction, since a fi-nite
distortion is found only within a limited region in wavevector space
at small wavevectors, where the corre-sponding integrands are relatively
small. |
