TY - JOUR
AU - Fang, X.
AU - Speldrich, M.
AU - Schilder, H.
AU - Cao, R.
AU - O'Halloran, K.P.
AU - Hill, C.L.
AU - Kögerler, P.
TI - Switching slow relaxation in a MnIII3MnIV cluster: an example of grafting single-molecule magnets onto polyoxometalates
JO - Chemical communications
VL - 46
SN - 1359-7345
CY - Cambridge
PB - Soc.
M1 - PreJuSER-13704
SP - 2760 - 2762
PY - 2010
N1 - Support for this work by the NSC, Taiwan, and ROC through the project NSC-98-2113-M-008-009 is greatly acknowledged.
AB - Binding an established single-molecule magnet cluster of distorted cubane type [Mn(III)(3)Mn(IV)O(4)] to the lacunary site of an {alpha-P(2)W(15)} polyoxotungstate scaffold results in a surprising zero-field splitting inversion and the subsequent loss of magnetization bistability.
KW - J (WoSType)
LB - PUB:(DE-HGF)16
C6 - pmid:20369174
UR - <Go to ISI:>//WOS:000276376000013
DO - DOI:10.1039/b925947c
UR - https://juser.fz-juelich.de/record/13704
ER -