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@BOOK{Basu:137092,
author = {Basu, Abhijit},
title = {{A}n analysis of the global atmospheric methane budget
under different climates},
volume = {168},
school = {Universität Köln},
type = {Dr.},
address = {Jülich},
publisher = {Forschungszentrum Jülich GmbH Zentralbibliothek, Verlag},
reportid = {FZJ-2013-03568},
isbn = {978-3-89336-859-4},
series = {Schriftenreihe des Forschungszentrums Jülich Reihe Energie
$\&$ Umwelt, Energy $\&$ Environment},
pages = {111 p.},
year = {2013},
note = {Universität Köln, Diss., 2013},
abstract = {Methane is the second most important gas after CO$_{2}$ in
the atmosphere in terms of radiative forcing. It also plays
an important role in tropospheric chemistry and influences
the oxidation capacity of atmosphere and amount of CO,
O$_{3}$ and water vapour. Various biogenic and anthropogenic
sectors including gas and oil extraction, wetlands, animal
ruminants emit methane in the atmosphere while it is mainly
OH which displaces it. At present, the mean global methane
concentration is balanced approximately at 1780 ppb after
undergoing several changes over the past decades. The
sources and sinks currently contribute between 450 and 510
Tg per year although the strength of each source components
suffers from uncertainty. Methane is also assumed to be a
key player in past climatic changes and its global abundance
underwent several transitions which were recorded in the ice
cores. One of the drastic changes in methane mixing ratio is
observed during the last glacial-interglacial transition, as
it shows an increasing trend from 350 ppb till it reaches
700 ppb at the pre-industrial Holocene. The post industrial
increase in global methane concentration is also
unprecedented. In this study, methane distribution at
present climate as well as at Last Glacial Maximum (LGM) and
pre-industrial era is simulated with a simplified global
tropospheric model ECHAM MOZ. For this simulation, methane
emissions from various inventories have been used. A new
parameterisation method is developed to estimate wetland
methane emission for present day which is later adapted for
LGM and pre-industrial time. Wetlands are the largest
natural source of methane, still suffers from huge
uncertainties. Contrary to the other hydrological models,
the present wetland parameterisation follows a simplified
approach based on a handful of soilparameters from CARAIB
vegetation model. This method is easily adaptable to past
climate simulations. The model result for present day from
ECHAM MOZ chemistry simulation has been validated with
station observation data across the globe and a set of
sensitivity analysis with the modified sources are carried
out to optimize the global methane budget. One of the major
findings from this study is the optimized wetland methane
strength which falls in the lower range of IPCC AR4 report.
The ECHAM MOZ transient simulation could produce the recent
methane trend and inter annual variability between 1990 and
2006 reasonably well although shows an underestimation in a
range of 20-40 ppb for the first eight years. This is
perhaps caused due to the underestimation of the oil and gas
extracted methane source used in the model. For LGM and
pre-industrial period, the model, using my wetland methane
source successfully reproduces the ice core methane records.
Compared to previous studies, the present LGM model source
strengthis weaker which raises the possibility of a less
deviated sink than present. This is supported by some recent
studies on the tropospheric oxidative chemistry which found
less OH variability than previously assumed. The important
aspect of the present study is that contrary to previous
studies where sinks are often hold responsible to explain
atmospheric methane variability, here the emphasis has been
given to the role of changing source based on these recent
findings.},
keywords = {Dissertation (GND)},
cin = {IEK-8},
cid = {I:(DE-Juel1)IEK-8-20101013},
pnm = {233 - Trace gas and aerosol processes in the troposphere
(POF2-233)},
pid = {G:(DE-HGF)POF2-233},
typ = {PUB:(DE-HGF)3},
url = {https://juser.fz-juelich.de/record/137092},
}