000137396 001__ 137396
000137396 005__ 20240619092043.0
000137396 0247_ $$2doi$$a10.1021/ma3025927
000137396 0247_ $$2ISSN$$a1520-5835
000137396 0247_ $$2ISSN$$a0024-9297
000137396 0247_ $$2WOS$$aWOS:000323193300051
000137396 0247_ $$2MLZ$$adoi:10.1021/ma3025927
000137396 037__ $$aFZJ-2013-03843
000137396 082__ $$a540
000137396 1001_ $$0P:(DE-Juel1)130870$$aNusser, Klaus$$b0$$eCorresponding Author
000137396 245__ $$aRheology and Anomalous Flow Properties of Poly(ethylene- alt -propylene)–Silica Nanocomposites
000137396 260__ $$aWashington, DC$$bSoc.$$c2013
000137396 3367_ $$0PUB:(DE-HGF)16$$2PUB:(DE-HGF)$$aJournal Article$$bjournal$$mjournal$$s1429770129_1892
000137396 3367_ $$2DataCite$$aOutput Types/Journal article
000137396 3367_ $$00$$2EndNote$$aJournal Article
000137396 3367_ $$2BibTeX$$aARTICLE
000137396 3367_ $$2ORCID$$aJOURNAL_ARTICLE
000137396 3367_ $$2DRIVER$$aarticle
000137396 520__ $$aIn this work, poly(ethylene-alt-propylene)–silica nanocomposites, constituting a model nanocomposite system with mostly nonattractive interactions, are studied by means of oscillatory shear rheology. Two different molecular weights were used in order to consider both the effect of nanoparticle presence on the relaxation of short as well as long polymer matrices. An increase of the particle fraction leads on the one hand to the observation of typical characteristics of colloidal rheology such as mechanical reinforcement and the formation of a particle gel. On the other hand and in the focus of our analysis, the increasing particle presence also directly affects the relaxation of the polymer chains. In particular, a shift of the polymer loss maximum in G″(ω) is found in the entangled matrices, whereas anomalous flow behavior is evidenced in the rheology data of highly filled short matrices. We succeeded to explain these macroscopic observations from the rheology experiments by considering small-angle neutron scattering and neutron spin echo results on the same samples, which yield detailed insight into the molecular circumstances responsible for the observed macroscopic property changes.
000137396 536__ $$0G:(DE-HGF)POF2-451$$a451 - Soft Matter Composites (POF2-451)$$cPOF2-451$$fPOF II$$x0
000137396 588__ $$aDataset connected to CrossRef, juser.fz-juelich.de
000137396 65027 $$0V:(DE-MLZ)SciArea-210$$2V:(DE-HGF)$$aSoft Condensed Matter$$x0
000137396 65017 $$0V:(DE-MLZ)GC-2004-2016$$2V:(DE-HGF)$$aBasic research$$x2
000137396 65017 $$0V:(DE-MLZ)GC-180$$2V:(DE-HGF)$$aOthers$$x1
000137396 65017 $$0V:(DE-MLZ)GC-140$$2V:(DE-HGF)$$aSoft Matter, Macromolecules, Complex fluids, Biophysics $$x0
000137396 693__ $$0EXP:(DE-MLZ)External-20140101$$5EXP:(DE-MLZ)External-20140101$$eMeasurement at external facility$$x0
000137396 7001_ $$0P:(DE-Juel1)130949$$aSchneider, Gerald Johannes$$b1$$eCorresponding author
000137396 7001_ $$0P:(DE-Juel1)130917$$aRichter, Dieter$$b2
000137396 773__ $$0PERI:(DE-600)1491942-4$$a10.1021/ma3025927$$gVol. 46, no. 15, p. 6263 - 6272$$n15$$p6263 - 6272$$tMacromolecules$$v46$$x1520-5835$$y2013
000137396 8564_ $$zPublished final document.
000137396 8564_ $$uhttps://juser.fz-juelich.de/record/137396/files/FZJ-2013-03843.pdf$$yRestricted$$zPublished final document.
000137396 909CO $$ooai:juser.fz-juelich.de:137396$$pVDB$$pVDB:MLZ
000137396 9101_ $$0I:(DE-588b)5008462-8$$6P:(DE-Juel1)130870$$aForschungszentrum Jülich GmbH$$b0$$kFZJ
000137396 9101_ $$0I:(DE-588b)5008462-8$$6P:(DE-Juel1)130949$$aForschungszentrum Jülich GmbH$$b1$$kFZJ
000137396 9101_ $$0I:(DE-588b)5008462-8$$6P:(DE-Juel1)130917$$aForschungszentrum Jülich GmbH$$b2$$kFZJ
000137396 9132_ $$0G:(DE-HGF)POF3-621$$1G:(DE-HGF)POF3-620$$2G:(DE-HGF)POF3-600$$9G:(DE-HGF)POF3-6215$$aDE-HGF$$bForschungsbereich Materie$$lVon Materie zu Materialien und Leben$$vIn-house research on the structure, dynamics and function of matter$$x0
000137396 9132_ $$0G:(DE-HGF)POF3-600$$1G:(DE-HGF)POF3$$2G:(DE-HGF)POF$$9G:(DE-HGF)POF3-6G15$$aDE-HGF$$bProgrammorientierte Förderung$$lPOF III$$vForschungsbereich Materie$$x1
000137396 9132_ $$0G:(DE-HGF)POF3-623$$1G:(DE-HGF)POF3-620$$2G:(DE-HGF)POF3-600$$9G:(DE-HGF)POF3-6G4$$aDE-HGF$$bForschungsbereich Materie$$lVon Materie zu Materialien und Leben$$vFacility topic: Neutrons for Research on Condensed Matter$$x2
000137396 9131_ $$0G:(DE-HGF)POF2-451$$1G:(DE-HGF)POF2-450$$2G:(DE-HGF)POF2-400$$3G:(DE-HGF)POF2$$4G:(DE-HGF)POF$$aDE-HGF$$bSchlüsseltechnologien$$lBioSoft$$vSoft Matter Composites$$x0
000137396 9141_ $$y2013
000137396 915__ $$0StatID:(DE-HGF)0010$$2StatID$$aJCR/ISI refereed
000137396 915__ $$0StatID:(DE-HGF)0100$$2StatID$$aJCR
000137396 915__ $$0StatID:(DE-HGF)0110$$2StatID$$aWoS$$bScience Citation Index
000137396 915__ $$0StatID:(DE-HGF)0111$$2StatID$$aWoS$$bScience Citation Index Expanded
000137396 915__ $$0StatID:(DE-HGF)0150$$2StatID$$aDBCoverage$$bWeb of Science Core Collection
000137396 915__ $$0StatID:(DE-HGF)0199$$2StatID$$aDBCoverage$$bThomson Reuters Master Journal List
000137396 915__ $$0StatID:(DE-HGF)0200$$2StatID$$aDBCoverage$$bSCOPUS
000137396 915__ $$0StatID:(DE-HGF)0300$$2StatID$$aDBCoverage$$bMedline
000137396 915__ $$0StatID:(DE-HGF)0310$$2StatID$$aDBCoverage$$bNCBI Molecular Biology Database
000137396 915__ $$0StatID:(DE-HGF)0420$$2StatID$$aNationallizenz
000137396 915__ $$0StatID:(DE-HGF)1040$$2StatID$$aDBCoverage$$bZoological Record
000137396 9201_ $$0I:(DE-Juel1)JCNS-1-20110106$$kNeutronenstreuung ; JCNS-1$$lNeutronenstreuung $$x0
000137396 9201_ $$0I:(DE-Juel1)JCNS-FRM-II-20110218$$kJCNS (München) ; Jülich Centre for Neutron Science JCNS (München) ; JCNS-FRM-II$$lJCNS-FRM-II$$x1
000137396 9201_ $$0I:(DE-Juel1)ICS-1-20110106$$kICS-1$$lNeutronenstreuung $$x2
000137396 980__ $$ajournal
000137396 980__ $$aVDB
000137396 980__ $$aI:(DE-Juel1)JCNS-1-20110106
000137396 980__ $$aI:(DE-Juel1)JCNS-FRM-II-20110218
000137396 980__ $$aI:(DE-Juel1)ICS-1-20110106
000137396 980__ $$aUNRESTRICTED
000137396 981__ $$aI:(DE-Juel1)IBI-8-20200312
000137396 981__ $$aI:(DE-Juel1)JCNS-1-20110106
000137396 981__ $$aI:(DE-Juel1)JCNS-FRM-II-20110218
000137396 981__ $$aI:(DE-Juel1)ICS-1-20110106