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@ARTICLE{Karthuser:13991,
      author       = {Karthäuser, S.},
      title        = {{C}ontrol {M}olecule-based {T}ransport for {F}uture
                      {M}olecular {D}evices},
      journal      = {Journal of physics / Condensed matter},
      volume       = {23},
      issn         = {0953-8984},
      address      = {Bristol},
      publisher    = {IOP Publ.},
      reportid     = {PreJuSER-13991},
      pages        = {013001},
      year         = {2011},
      note         = {I grateful acknowledge Professors Rainer Waser, Harold J W
                      Zandvliet, Drs Christina Lennartz and Peter Kowalzik for
                      helpful discussions. This work was partially supported by
                      the EU FP7 project MOLOC and the 'Deutsche
                      Forschungsgemeinschaft' (DFG).},
      abstract     = {In this review, possibilities to modify intentionally the
                      electronic transport properties of metal/molecule/metal
                      devices (MMM devices) are discussed. Here especially the
                      influence of the metal work function, the metal-molecule
                      interface, the molecule dipole and different tunneling
                      mechanisms are considered. A route to evaluate the effective
                      surface work function of metal-molecule systems is given
                      and, based on experimental results, an exemplary estimation
                      is performed. The electron transport across different
                      metal-molecule interfaces is characterized by relating
                      transmission coefficients extracted from experimentally
                      derived molecular conductances, decay constants or tunneling
                      barrier heights. Based on the reported results the tunneling
                      decay constant can be assumed to be suitable to characterize
                      intrinsic molecular electron transport properties, while the
                      nature of the metal-molecule contacts is properly described
                      by the transmission coefficient. A clear gradation of
                      transmission efficiencies of metal-anchoring group
                      combinations can be given.},
      keywords     = {J (WoSType)},
      cin          = {PGI-7 / JARA-FIT},
      ddc          = {530},
      cid          = {I:(DE-Juel1)PGI-7-20110106 / $I:(DE-82)080009_20140620$},
      pnm          = {Grundlagen für zukünftige Informationstechnologien},
      pid          = {G:(DE-Juel1)FUEK412},
      shelfmark    = {Physics, Condensed Matter},
      typ          = {PUB:(DE-HGF)16},
      pubmed       = {pmid:21406815},
      UT           = {WOS:000285003400002},
      doi          = {10.1088/0953-8984/23/1/013001},
      url          = {https://juser.fz-juelich.de/record/13991},
}