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@ARTICLE{Roescher:14008,
author = {Roescher, M. and Schneller, T. and Waser, R.},
title = {{C}omments on the processing of the niobium omponent for
chemical solution derived niobium oxide-based thin films},
journal = {Journal of sol gel science and technology},
volume = {56},
issn = {0928-0707},
address = {Dordrecht [u.a.]},
publisher = {Springer Science + Business Media B.V},
reportid = {PreJuSER-14008},
pages = {236 - 243},
year = {2010},
note = {This work was supported by the Hans. L. Merkle Foundation
for the Association for the Promotion of Science and
Humanities in Germany (Grant T 113/16679/07).},
abstract = {The impact of chemical precursor modification on the
electronic properties of chemical solution deposition
derived niobium oxide thin-films has been evaluated. It has
been found that the application of certain chemical
modifications is mandatory in order to obtain electrically
insulating thin-films at low processing temperatures. It is
emphasized that the devised optimal way of processing for
the niobium component is widely contrary to the solution
based processing of potassium sodium niobate films reported
so far. Regarding the physical nature of the observed
instabilities, the phase evolution of solution processed
niobium oxide films has been studied. It has been detected
that the organic fraction in the precursor solution is
stable up to high temperatures and as a result, the low
temperature crystalline TT-phase of niobium oxide is
preserved up to unusually high processing temperatures. The
inherent structural distortion of the unit cells may present
a new defect mechanism that has to be further investigated
regarding the inferior ferroelectric properties of chemical
solution derived potassium sodium niobate thin-films, which
are often observed.},
keywords = {J (WoSType)},
cin = {IFF-6 / JARA-FIT},
ddc = {600},
cid = {I:(DE-Juel1)VDB786 / $I:(DE-82)080009_20140620$},
pnm = {Grundlagen für zukünftige Informationstechnologien},
pid = {G:(DE-Juel1)FUEK412},
shelfmark = {Materials Science, Ceramics},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000284611500003},
doi = {10.1007/s10971-010-2299-1},
url = {https://juser.fz-juelich.de/record/14008},
}