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@ARTICLE{Bras:141042,
author = {Bras, Ana and Hövelmann, Claas and Antonius, Wiebke and
Teixeira, José and Radulescu, Aurel and Allgaier, J. and
Pyckhout-Hintzen, Wim and Wischnewski, Andreas and Richter,
Dieter},
title = {{M}olecular {A}pproach to {S}upramolecular {P}olymer
{A}ssembly by {S}mall {A}ngle {N}eutron {S}cattering},
journal = {Macromolecules},
volume = {46},
number = {23},
issn = {1520-5835},
address = {Washington, DC},
publisher = {Soc.},
reportid = {FZJ-2013-06245},
pages = {9446 - 9454},
year = {2013},
abstract = {We present a small angle neutron scattering (SANS) study of
the association of heterocomplementary telechelic
polypropylene glycol (PPG) polymers, bearing either
diaminotriazine (DAT) or thymine (Thy) stickers as
end-groups, both in the melt and in dilute solution. The
SANS data are critically examined for the architecture and
morphology as well as relative extent of linear assembly in
the apolar solvent toluene. A random phase approximation
(RPA) approach, adapted for a supramolecularly assembled
multiblock copolymer is presented, which allows to extract
the interaction parameters between the constituents and the
medium. From the proposed approach, which describes very
well heterocomplementary hydrogen-bonding telechelic
polymers in both diluted toluene solution and in the melt,
we conclude that linear association prevails},
cin = {ICS-1 / Neutronenstreuung ; JCNS-1 / JCNS (München) ;
Jülich Centre for Neutron Science JCNS (München) ;
JCNS-FRM-II},
ddc = {540},
cid = {I:(DE-Juel1)ICS-1-20110106 / I:(DE-Juel1)JCNS-1-20110106 /
I:(DE-Juel1)JCNS-FRM-II-20110218},
pnm = {451 - Soft Matter Composites (POF2-451) / 54G - JCNS
(POF2-54G24)},
pid = {G:(DE-HGF)POF2-451 / G:(DE-HGF)POF2-54G24},
experiment = {EXP:(DE-MLZ)KWS2-20140101},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000328436800030},
doi = {10.1021/ma401714r},
url = {https://juser.fz-juelich.de/record/141042},
}