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@ARTICLE{Heinen:14115,
author = {Heinen, M. and Holmqvist, P. and Banchio, A.J. and Nägele,
G.},
title = {{P}air structure of the hard-sphere {Y}ukawa fluid: {A}n
improved analytic method versus simulations,
{R}ogers-{Y}oung scheme, and experiment},
journal = {The journal of chemical physics},
volume = {134},
issn = {0021-9606},
address = {Melville, NY},
publisher = {American Institute of Physics},
reportid = {PreJuSER-14115},
pages = {044532},
year = {2011},
note = {We thank S. Rogers, J. Gapinski and A. Patkowski for
helpful discussions. M. H. acknowledges support by the
International Helmholtz Research School of Biophysics and
Soft Matter (IHRS BioSoft). A. J. B. acknowledges financial
support from SeCyT-UNC and CONICET. This work was under
appropriation of funds from the Deutsche
Forschungsgemeinschaft (SFB-TR6, project B2).},
abstract = {We present a comprehensive study of the equilibrium pair
structure in fluids of nonoverlapping spheres interacting by
a repulsive Yukawa-like pair potential, with special focus
on suspensions of charged colloidal particles. The accuracy
of several integral equation schemes for the static
structure factor, S(q), and radial distribution function,
g(r), is investigated in comparison to computer simulation
results and static light scattering data on
charge-stabilized silica spheres. In particular, we show
that an improved version of the so-called
penetrating-background corrected rescaled mean spherical
approximation (PB-RMSA) by Snook and Hayter [Langmuir 8,
2880 (1992)], referred to as the modified PB-RMSA
(MPB-RMSA), gives pair structure functions which are in
general in very good agreement with Monte Carlo simulations
and results from the accurate but nonanalytical and
therefore computationally more expensive Rogers-Young
integral equation scheme. The MPB-RMSA preserves the
analytic simplicity of the standard rescaled mean spherical
(RMSA) solution. The combination of high accuracy and fast
evaluation makes the MPB-RMSA ideally suited for extensive
parameter scans and experimental data evaluation, and for
providing the static input to dynamic theories. We discuss
the results of extensive parameter scans probing the
concentration scaling of the pair structure of strongly
correlated Yukawa particles, and we determine the
liquid-solid coexistence line using the Hansen-Verlet
freezing rule.},
keywords = {J (WoSType)},
cin = {ICS-3},
ddc = {540},
cid = {I:(DE-Juel1)ICS-3-20110106},
pnm = {BioSoft: Makromolekulare Systeme und biologische
Informationsverarbeitung},
pid = {G:(DE-Juel1)FUEK505},
shelfmark = {Physics, Atomic, Molecular $\&$ Chemical},
typ = {PUB:(DE-HGF)16},
pubmed = {pmid:21280773},
UT = {WOS:000286897600098},
doi = {10.1063/1.3524309},
url = {https://juser.fz-juelich.de/record/14115},
}