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000014249 0247_ $$2DOI$$a10.1039/C0CP02044C
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000014249 0247_ $$2ISSN$$a1463-9076
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000014249 0247_ $$2MLZ$$aWellertKHRH2011
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000014249 041__ $$aeng
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000014249 084__ $$2WoS$$aChemistry, Physical
000014249 084__ $$2WoS$$aPhysics, Atomic, Molecular & Chemical
000014249 1001_ $$0P:(DE-HGF)0$$aWellert, S.$$b0
000014249 245__ $$aTemperature dependence of the surfactant film bending elasticity in a bicontinuous sugar surfactant based microemulsion: a quasielastic scattering study
000014249 260__ $$aCambridge$$bRSC Publ.$$c2011
000014249 300__ $$a3092 - 3099
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000014249 440_0 $$04916$$aPhysical Chemistry Chemical Physics$$v13$$x1463-9076$$y8
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000014249 520__ $$aCurrently, the design of microemulsions is focussed on the formulation of environmentally compatible systems formed by non-harmful amphiphiles and oils. The use of sugar-based surfactants allows the design of microemulsions where, instead of the temperature, the addition of short- or medium-chain alcohols tunes the curvature of the amphiphilic interface. In this work, the resulting temperature stability of a sugar surfactant and rapeseed methyl ester based bicontinuous microemulsion is exploited to study the influence of temperature variations on the bending elastic constant κ. Quasi-elastic scattering of light and neutrons is used to separate long-range collective motions and local thermally excited undulations of the interface. κ in units of kT is found to be independent of temperature over a wide range.
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000014249 650_2 $$2MeSH$$aCarbohydrates: chemistry
000014249 650_2 $$2MeSH$$aElasticity
000014249 650_2 $$2MeSH$$aEmulsions: chemistry
000014249 650_2 $$2MeSH$$aLight
000014249 650_2 $$2MeSH$$aScattering, Radiation
000014249 650_2 $$2MeSH$$aScattering, Small Angle
000014249 650_2 $$2MeSH$$aSurface-Active Agents: chemistry
000014249 650_2 $$2MeSH$$aTemperature
000014249 650_2 $$2MeSH$$aX-Ray Diffraction
000014249 650_7 $$00$$2NLM Chemicals$$aCarbohydrates
000014249 650_7 $$00$$2NLM Chemicals$$aEmulsions
000014249 650_7 $$00$$2NLM Chemicals$$aSurface-Active Agents
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000014249 693__ $$0EXP:(DE-MLZ)J-NSE-20140101$$1EXP:(DE-MLZ)FRMII-20140101$$5EXP:(DE-MLZ)J-NSE-20140101$$6EXP:(DE-MLZ)NL2ao-20140101$$aForschungs-Neutronenquelle Heinz Maier-Leibnitz$$eJ-NSE: Neutron spin-echo spectrometer$$fNL2ao$$x0
000014249 7001_ $$0P:(DE-HGF)0$$aKarg, M.$$b1
000014249 7001_ $$0P:(DE-Juel1)130718$$aHolderer, O.$$b2$$uFZJ
000014249 7001_ $$0P:(DE-HGF)0$$aRichardt, A.$$b3
000014249 7001_ $$0P:(DE-HGF)0$$aHellweg, T.$$b4
000014249 773__ $$0PERI:(DE-600)1476244-4$$a10.1039/c0cp02044c$$gVol. 13, p. 3092 - 3099$$p3092 - 3099$$q13<3092 - 3099$$tPhysical Chemistry Chemical Physics$$v13$$x1463-9076$$y2011
000014249 8567_ $$uhttp://dx.doi.org/10.1039/C0CP02044C
000014249 8564_ $$uhttps://juser.fz-juelich.de/record/14249/files/FZJ-14249.pdf$$yPublished under German "Allianz" Licensing conditions on 2010-12-10. Available in OpenAccess from 2011-12-10$$zPublished final document.
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