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024 7 _ |a 10.1209/0295-5075/93/54004
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|a Physics, Multidisciplinary
100 1 _ |0 P:(DE-Juel1)VDB97976
|a Huang, C.-C.
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245 _ _ |a Tumbling of polymers in semidilute solution under shear flow
260 _ _ |a Les Ulis
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|c 2011
300 _ _ |a 54004
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440 _ 0 |0 1996
|a Europhysics Letters
|v 93
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|y 5
500 _ _ |a Financial support by the Deutsche Forschungsgemeinschaft within SFB TR6 is gratefully acknowledged. We are grateful to the Julich Supercomputer Centre (JSC) for allocation of a special CPU-time grant.
520 _ _ |a The tumbling dynamics of individual polymers in semidilute solution is studied by large-scale non-equilibrium mesoscale hydrodynamic simulations. We find that the tumbling time is equal to the non-equilibrium relaxation time of the polymer end-to-end distance along the flow direction and strongly depends on concentration. In addition, the normalized tumbling frequency as well as the widths of the alignment distribution functions for a given concentration-dependent Weissenberg number exhibit a weak concentration dependence in the cross-over regime from a dilute to a semidilute solution. For semidilute solutions a universal behavior is obtained. This is a consequence of screening of hydrodynamic interactions at polymer concentrations exceeding the overlap concentration. Copyright (c) EPLA, 2011
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700 1 _ |0 P:(DE-Juel1)131039
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856 7 _ |u http://dx.doi.org/10.1209/0295-5075/93/54004
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