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@ARTICLE{Busch:14703,
author = {Busch, P. and Rauscher, M. and Moulin, J.-F. and
Müller-Buschbaum, P.},
title = {{D}ebye-{S}cherrer rings from block copolymer films with
power-like order},
journal = {Journal of applied crystallography},
volume = {44},
issn = {0021-8898},
address = {Copenhagen},
publisher = {Munksgaard},
reportid = {PreJuSER-14703},
pages = {370 - 379},
year = {2011},
note = {CHESS is a national user facility supported by the National
Science Foundation and the National Institutes of
Health/National Institute of General Medical Sciences under
award No. DMR-0225180. We thank Sita Krishnan for the
preparation of the semifluorinated diblock copolymer sample.
PMB acknowledges financial support by the Deutsche
Forschungsgemeinschaft in project No. MU1487/6.},
abstract = {The powder-like orientation of lamellar domains in thin
films of the diblock copolymer polystyrene-block-poly(methyl
methacrylate) is investigated using grazing-incidence
small-angle X-ray scattering (GISAXS) and grazing-incidence
small-angle neutron scattering (GISANS). Conventional
monochromatic GISANS and GISAXS measurements are compared
with neutron time-of-flight GISANS. For angles of incidence
and exit larger than the critical angle of total external
reflection of the polymer, Debye-Scherrer rings are
observed. The position of the Debye-Scherrer rings is
described quantitatively based on a reduced version of the
distorted-wave Born approximation. A strong distortion of
the ring shape is caused by refraction and reflections from
the film interfaces. Close to the critical angle, the ring
shape collapses into a banana shape.},
keywords = {J (WoSType)},
cin = {PGI-4 / JCNS (München) ; Jülich Centre for Neutron
Science JCNS (München) ; JCNS-FRM-II / JCNS-1 / JCNS-2},
ddc = {540},
cid = {I:(DE-Juel1)PGI-4-20110106 /
I:(DE-Juel1)JCNS-FRM-II-20110218 /
I:(DE-Juel1)JCNS-1-20110106 / I:(DE-Juel1)JCNS-2-20110106},
pnm = {BioSoft: Makromolekulare Systeme und biologische
Informationsverarbeitung / Großgeräte für die Forschung
mit Photonen, Neutronen und Ionen (PNI)},
pid = {G:(DE-Juel1)FUEK505 / G:(DE-Juel1)FUEK415},
experiment = {EXP:(DE-MLZ)KWS2-20140101 / EXP:(DE-MLZ)REFSANS-20140101},
shelfmark = {Crystallography},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000288758500014},
doi = {10.1107/S0021889810053823},
url = {https://juser.fz-juelich.de/record/14703},
}