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000150483 1001_ $$0P:(DE-HGF)0$$aEl-Kareh, L.$$b0$$eCorresponding author
000150483 245__ $$aSelf-assembled monolayers of methylselenolate on the Au(111) surface: A combined STM and DFT study
000150483 260__ $$aAmsterdam$$bElsevier$$c2014
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000150483 520__ $$aIn this study scanning tunneling microscopy (STM) and density functional theory (DFT) were used to investigate the structural formation of methylselenolate (CH3Se) self-assembled monolayers (SAMs) on the Au(111) surface. SAMs were prepared by two different methods, from solution and by exposing the Au(111) surface to gaseous dimethyldiselenide (DMDSe). For methylselenolate (MSe) on the Au(111) surface, our STM measurements revealed the presence of (4 × √3) and (3 × 2√3) rectangular striped phases. These structures were verified by DFT calculations. For both phases, the DFT calculations clearly found a bridge adsorption geometry for MSe on Au(111). Furthermore, they provide information about the electronic structure of the MSe–SAMs.
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000150483 7001_ $$0P:(DE-HGF)0$$aWestphal, C.$$b6
000150483 773__ $$0PERI:(DE-600)1479030-0$$a10.1016/j.susc.2013.09.018$$gVol. 619, p. 67 - 70$$p67 - 70$$tSurface science$$v619$$x0039-6028$$y2014
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