000150933 001__ 150933
000150933 005__ 20210129213331.0
000150933 0247_ $$2doi$$a10.1007/s10311-013-0447-x
000150933 0247_ $$2ISSN$$a1610-3661
000150933 0247_ $$2ISSN$$a1610-3653
000150933 0247_ $$2WOS$$aWOS:000335662000009
000150933 037__ $$aFZJ-2014-00966
000150933 082__ $$a540
000150933 1001_ $$0P:(DE-HGF)0$$aChen, Lei$$b0$$eCorresponding author
000150933 245__ $$aOnline electro-Fenton-mass spectrometry reveals 2,4′,5-trichlorobiphenyl oxidation products and binding to organic matter
000150933 260__ $$aBerlin [u.a.]$$bSpringer$$c2014
000150933 3367_ $$0PUB:(DE-HGF)16$$2PUB:(DE-HGF)$$aJournal Article$$bjournal$$mjournal$$s1399628609_27975
000150933 3367_ $$2DataCite$$aOutput Types/Journal article
000150933 3367_ $$00$$2EndNote$$aJournal Article
000150933 3367_ $$2BibTeX$$aARTICLE
000150933 3367_ $$2ORCID$$aJOURNAL_ARTICLE
000150933 3367_ $$2DRIVER$$aarticle
000150933 520__ $$aElectrochemistry–mass spectrometry is used to simulate redox reactions in many research disciplines because this technique is fast and provides information on compound metabolites. However, the analysis of the degradation of refractory organic pollutants by reactive oxygen species is difficult to achieve by the electrochemistry step. Therefore, here we use online electro-Fenton-mass spectrometry to study for the first time the oxidation of 2,4′,5-trichlorobiphenyl [polychlorinated biphenyl (PCB) 31] by reactive oxygen species and the binding reactions of PCB degradation products with model substances of natural organic matter. The degradation products were identified by coupled Q Trap mass spectrometry. We observed a binding of a degradation product with γ-l-glutamyl-l-cysteinyl-glycine. We propose a transformation pathway. We conclude that online electro-Fenton-mass spectrometry is a promising technique to study the oxidation of refractory organic pollutants and further binding of degradation products with natural organic matter.
000150933 536__ $$0G:(DE-HGF)POF3-211$$a211 - Global Processes: Integrated Monitoring and Modelling (POF3-211)$$cPOF3-211$$fPOF III$$x0
000150933 588__ $$aDataset connected to CrossRef, juser.fz-juelich.de
000150933 7001_ $$0P:(DE-Juel1)133844$$aKüppers, Stephan$$b1
000150933 7001_ $$0P:(DE-HGF)0$$aWang, Zheng$$b2
000150933 7001_ $$0P:(DE-HGF)0$$aXiang, Xinyi$$b3
000150933 7001_ $$0P:(DE-HGF)0$$aCao, Shiwei$$b4
000150933 773__ $$0PERI:(DE-600)2107984-5$$a10.1007/s10311-013-0447-x$$n2$$p329-334$$tEnvironmental chemistry letters$$v12$$x1610-3661$$y2014
000150933 8564_ $$uhttps://juser.fz-juelich.de/record/150933/files/FZJ-2014-00966.pdf$$yRestricted$$zPublished final document.
000150933 909CO $$ooai:juser.fz-juelich.de:150933$$pVDB:Earth_Environment$$pVDB
000150933 9101_ $$0I:(DE-Juel1)ZEA-3-20090406$$6P:(DE-Juel1)133844$$aAnalytik$$b1$$kZEA-3
000150933 9132_ $$0G:(DE-HGF)POF3-255$$1G:(DE-HGF)POF3-250$$2G:(DE-HGF)POF3-200$$aDE-HGF$$bMarine, Küsten- und Polare Systeme$$lTerrestrische Umwelt$$vTerrestrial Systems: From Observation to Prediction$$x0
000150933 9131_ $$0G:(DE-HGF)POF3-211$$1G:(DE-HGF)POF3-210$$2G:(DE-HGF)POF3-200$$3G:(DE-HGF)POF3$$4G:(DE-HGF)POF$$aDE-HGF$$bErde und Umwelt$$lGeosystem - Erde im Wandel$$vGlobal Processes: Integrated Monitoring and Modelling$$x0
000150933 9141_ $$y2014
000150933 915__ $$0StatID:(DE-HGF)0010$$2StatID$$aJCR/ISI refereed
000150933 915__ $$0StatID:(DE-HGF)0100$$2StatID$$aJCR
000150933 915__ $$0StatID:(DE-HGF)0111$$2StatID$$aWoS$$bScience Citation Index Expanded
000150933 915__ $$0StatID:(DE-HGF)0150$$2StatID$$aDBCoverage$$bWeb of Science Core Collection
000150933 915__ $$0StatID:(DE-HGF)0199$$2StatID$$aDBCoverage$$bThomson Reuters Master Journal List
000150933 915__ $$0StatID:(DE-HGF)0200$$2StatID$$aDBCoverage$$bSCOPUS
000150933 915__ $$0StatID:(DE-HGF)0300$$2StatID$$aDBCoverage$$bMedline
000150933 915__ $$0StatID:(DE-HGF)1040$$2StatID$$aDBCoverage$$bZoological Record
000150933 915__ $$0StatID:(DE-HGF)1060$$2StatID$$aDBCoverage$$bCurrent Contents - Agriculture, Biology and Environmental Sciences
000150933 9201_ $$0I:(DE-Juel1)ZEA-3-20090406$$kZEA-3$$lAnalytik$$x0
000150933 980__ $$ajournal
000150933 980__ $$aVDB
000150933 980__ $$aI:(DE-Juel1)ZEA-3-20090406
000150933 980__ $$aUNRESTRICTED