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@ARTICLE{Chen:150933,
      author       = {Chen, Lei and Küppers, Stephan and Wang, Zheng and Xiang,
                      Xinyi and Cao, Shiwei},
      title        = {{O}nline electro-{F}enton-mass spectrometry reveals
                      2,4′,5-trichlorobiphenyl oxidation products and binding to
                      organic matter},
      journal      = {Environmental chemistry letters},
      volume       = {12},
      number       = {2},
      issn         = {1610-3661},
      address      = {Berlin [u.a.]},
      publisher    = {Springer},
      reportid     = {FZJ-2014-00966},
      pages        = {329-334},
      year         = {2014},
      abstract     = {Electrochemistry–mass spectrometry is used to simulate
                      redox reactions in many research disciplines because this
                      technique is fast and provides information on compound
                      metabolites. However, the analysis of the degradation of
                      refractory organic pollutants by reactive oxygen species is
                      difficult to achieve by the electrochemistry step.
                      Therefore, here we use online electro-Fenton-mass
                      spectrometry to study for the first time the oxidation of
                      2,4′,5-trichlorobiphenyl [polychlorinated biphenyl (PCB)
                      31] by reactive oxygen species and the binding reactions of
                      PCB degradation products with model substances of natural
                      organic matter. The degradation products were identified by
                      coupled Q Trap mass spectrometry. We observed a binding of a
                      degradation product with γ-l-glutamyl-l-cysteinyl-glycine.
                      We propose a transformation pathway. We conclude that online
                      electro-Fenton-mass spectrometry is a promising technique to
                      study the oxidation of refractory organic pollutants and
                      further binding of degradation products with natural organic
                      matter.},
      cin          = {ZEA-3},
      ddc          = {540},
      cid          = {I:(DE-Juel1)ZEA-3-20090406},
      pnm          = {211 - Global Processes: Integrated Monitoring and Modelling
                      (POF3-211)},
      pid          = {G:(DE-HGF)POF3-211},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000335662000009},
      doi          = {10.1007/s10311-013-0447-x},
      url          = {https://juser.fz-juelich.de/record/150933},
}