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@ARTICLE{Hung:151099,
author = {Hung, Yu-Fu and Valdau, Olga and Schünke, Sven and Stern,
O and Koenig, Bernd W. and Willbold, Dieter and Hoffmann,
Silke},
title = {{R}ecombinant {P}roduction of the {A}mino {T}erminal
{C}ytoplasmic {R}egion of {D}engue {V}irus
{N}on-{S}tructural {P}rotein 4{A} for {S}tructural
{S}tudies},
journal = {PLoS one},
volume = {9},
number = {1},
issn = {1932-6203},
address = {Lawrence, Kan.},
publisher = {PLoS},
reportid = {FZJ-2014-01121},
pages = {e86482 (1 - 10)},
year = {2014},
abstract = {BACKGROUND:Dengue virus (DENV) is a mosquito-transmitted
positive single strand RNA virus belonging to the
Flaviviridae family. DENV causes dengue fever, currently the
world's fastest-spreading tropical disease. Severe forms of
the disease like dengue hemorrhagic fever and dengue shock
syndrome are life-threatening. There is no specific
treatment and no anti-DENV vaccines. Our recent data
suggests that the amino terminal cytoplasmic region of the
dengue virus non-structural protein 4A (NS4A) comprising
amino acid residues 1 to 48 forms an amphipathic helix in
the presence of membranes. Its amphipathic character was
shown to be essential for viral replication. NMR-based
structure-function analysis of the NS4A amino terminal
region depends on its milligram-scale production and
labeling with NMR active isotopes.METHODOLOGY/PRINCIPAL
FINDINGS:This report describes the optimization of a uniform
procedure for the expression and purification of the wild
type NS4A(1-48) peptide and a peptide derived from a
replication-deficient mutant NS4A(1-48; L6E, M10E) with
disrupted amphipathic nature. A codon-optimized, synthetic
gene for NS4A(1-48) was expressed as a fusion with a GST-GB1
dual tag in E. coli. Tobacco etch virus (TEV) protease
mediated cleavage generated NS4A(1-48) peptides without any
artificial overhang. Using the described protocol up to 4
milligrams of the wild type or up to 5 milligrams of the
mutant peptide were obtained from a one-liter culture.
Isotopic labeling of the peptides was achieved and initial
NMR spectra were recorded.CONCLUSIONS/SIGNIFICANCE:Small
molecules targeting amphipathic helices in the related
Hepatitis C virus were shown to inhibit viral replication,
representing a new class of antiviral drugs. These findings
highlight the need for an efficient procedure that provides
large quantities of the amphipathic helix containing NS4A
peptides. The double tag strategy presented in this
manuscript answers these needs yielding amounts that are
sufficient for comprehensive biophysical and structural
studies, which might reveal new drug targets.},
cin = {ICS-6},
ddc = {500},
cid = {I:(DE-Juel1)ICS-6-20110106},
pnm = {452 - Structural Biology (POF2-452)},
pid = {G:(DE-HGF)POF2-452},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000330288000105},
pubmed = {pmid:24466115},
doi = {10.1371/journal.pone.0086482},
url = {https://juser.fz-juelich.de/record/151099},
}