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@ARTICLE{Mercurio:151162,
author = {Mercurio, Giuseppe and Maurer, Reinhard J. and Hagen,
Sebastian and Leyssner, Felix and Meyer, Jörg and Tegeder,
Petra and Soubatch, Sergey and Reuter, Karsten and Tautz, F.
S.},
title = {{X}-ray standing wave simulations based on {F}ourier vector
analysis as a method to retrieve complex molecular
adsorption geometries},
journal = {Frontiers in physics},
volume = {2},
issn = {2296-424X},
address = {Lausanne},
publisher = {Frontiers Media},
reportid = {FZJ-2014-01161},
pages = {1-13/ 2},
year = {2014},
abstract = {We present an analysis method of normal incidence x-ray
standing wave (NIXSW) data that allows detailed adsorption
geometries of large and complex molecules to be retrieved.
This method (Fourier vector analysis) is based on the
comparison of both the coherence and phase of NIXSW data to
NIXSW simulations of different molecular geometries as the
relevant internal degrees of freedom are tuned. We introduce
this analysis method using the prototypical molecular switch
azobenzene (AB) adsorbed on the Ag(111) surface as a model
system. The application of the Fourier vector analysis to
AB/Ag(111) provides, on the one hand, detailed adsorption
geometries including dihedral angles, and on the other hand,
insights into the dynamics of molecules and their bonding to
the metal substrate. This analysis scheme is generally
applicable to any adsorbate, it is necessary for molecules
with potentially large distortions, and will be particularly
valuable for molecules whose distortion on adsorption can be
mapped on a limited number of internal degrees of freedom.},
cin = {PGI-3},
ddc = {530},
cid = {I:(DE-Juel1)PGI-3-20110106},
pnm = {142 - Controlling Spin-Based Phenomena (POF3-142)},
pid = {G:(DE-HGF)POF3-142},
typ = {PUB:(DE-HGF)16},
doi = {10.3389/fphy.2014.00002},
url = {https://juser.fz-juelich.de/record/151162},
}