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000015127 0247_ $$2DOI$$a10.1140/epje/i2011-11040-9
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000015127 041__ $$aeng
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000015127 084__ $$2WoS$$aChemistry, Physical
000015127 084__ $$2WoS$$aMaterials Science, Multidisciplinary
000015127 084__ $$2WoS$$aPhysics, Applied
000015127 084__ $$2WoS$$aPolymer Science
000015127 1001_ $$0P:(DE-Juel1)130616$$aDhont, J.K.G.$$b0$$uFZJ
000015127 245__ $$aElectric-field-induced polarization of the layer of condensed ions on cylindrical colloids
000015127 260__ $$aBerlin$$bSpringer$$c2011
000015127 300__ $$a40
000015127 3367_ $$0PUB:(DE-HGF)16$$2PUB:(DE-HGF)$$aJournal Article
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000015127 440_0 $$01985$$aEuropean Physical Journal E$$v34$$x1292-8941$$y4
000015127 500__ $$aThis work has significantly benefitted from many discussions with Prof. G.S. Manning. Part of this research was supported by the Trans-regio SFB 6018 "Physics of Colloidal Dispersions in External Fields" and by the EU-FP7 Network "NanoDirect" (contract number CP-FP-213948-2).
000015127 520__ $$aIn concentrated suspensions of charged colloids, interactions between colloids can be induced by an external electric field through the polarization of charge distributions (within the diffusive double layer and the layer of condensed ions) and/or electro-osmotic flow. In case of rod-like colloids, these field-induced inter-colloidal interactions have recently been shown to lead to anomalous orientation perpendicular to the external field, and to phase/state transitions and dynamical states, depending on the field amplitude and frequency of the external field. As a first step towards a (semi-) quantitative understanding of these phenomena, we present a linear-response analysis of the frequency-dependent polarization of the layer of condensed ions on a single, long and thin cylindrical colloid. The in-phase and out-phase response functions for the charge distribution and the electric potential are calculated for arbitrary orientation of the cylindrical colloid. The frequency-dependent degree of alignment, which is proportional to the electric-field-induced birefringence, is calculated as well, and compared to experiments on dilute fd virus suspensions.
000015127 536__ $$0G:(DE-Juel1)FUEK505$$2G:(DE-HGF)$$aBioSoft: Makromolekulare Systeme und biologische Informationsverarbeitung$$cP45$$x0
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000015127 650_2 $$2MeSH$$aAlgorithms
000015127 650_2 $$2MeSH$$aColloids: chemistry
000015127 650_2 $$2MeSH$$aElectricity
000015127 650_2 $$2MeSH$$aElectrochemistry: methods
000015127 650_2 $$2MeSH$$aElectrolytes
000015127 650_2 $$2MeSH$$aIons
000015127 650_2 $$2MeSH$$aMaterials Testing
000015127 650_2 $$2MeSH$$aModels, Chemical
000015127 650_2 $$2MeSH$$aModels, Statistical
000015127 650_2 $$2MeSH$$aParticle Size
000015127 650_2 $$2MeSH$$aPhysics: methods
000015127 650_2 $$2MeSH$$aSurface Properties
000015127 650_2 $$2MeSH$$aSuspensions
000015127 650_7 $$00$$2NLM Chemicals$$aColloids
000015127 650_7 $$00$$2NLM Chemicals$$aElectrolytes
000015127 650_7 $$00$$2NLM Chemicals$$aIons
000015127 650_7 $$00$$2NLM Chemicals$$aSuspensions
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000015127 7001_ $$0P:(DE-Juel1)130749$$aKang, K.$$b1$$uFZJ
000015127 773__ $$0PERI:(DE-600)2004003-9$$a10.1140/epje/i2011-11040-9$$gVol. 34, p. 40$$p40$$q34<40$$tThe @European physical journal / E$$v34$$x1292-8941$$y2011
000015127 8567_ $$uhttp://dx.doi.org/10.1140/epje/i2011-11040-9
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