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000151285 1001_ $$0P:(DE-Juel1)151337$$aMaccarrone, Simona$$b0$$eCorresponding author
000151285 245__ $$aAnchoring vs Bridging: New Findings on Polymer Additives in Bicontinuous Microemulsions
000151285 260__ $$aWashington, DC$$bACS Publ.$$c2014
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000151285 520__ $$aWe show for the first time the effect of telechelic polymers asadditives in bicontinuous microemulsions. We combined macroscopicobservations of the phase behavior with microscopic measurements of thestructure by small-angle neutron scattering (SANS) to recover the two elasticmoduli, κ and κ̅, namely the bending rigidity and saddle-splay modulus. Onthe basis of these results, we could classify the effect of telechelic polymersalong with confinement, expressed as the ratio of the polymer end-to-enddistance Ree and the oil−water domain size d. Their unique property to anchorat two points in the membrane (bridging) acts like a switch from antiboosterto booster of the surfactant efficiency (between low and ultralowconfinement). In the region of medium confinement, all telechelic polymersare in the bridging configuration and we have a maximum of the boostingeffect, while at high confinement, the reversed behavior is found whereanchoring and/or bridging do not play any role anymore.
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000151285 7001_ $$0P:(DE-Juel1)130501$$aAllgaier, J.$$b1$$ufzj
000151285 7001_ $$0P:(DE-Juel1)130646$$aFrielinghaus, Henrich$$b2
000151285 7001_ $$0P:(DE-Juel1)130917$$aRichter, Dieter$$b3
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