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| Hauptseite > Publikationsdatenbank > Anchoring vs Bridging: New Findings on Polymer Additives in Bicontinuous Microemulsions > print |
| Hauptseite > Publikationsdatenbank > Anchoring vs Bridging: New Findings on Polymer Additives in Bicontinuous Microemulsions > print |
| 001 | 151285 | ||
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| 024 | 7 | _ | |a 10.1021/la404354w |2 doi |
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| 037 | _ | _ | |a FZJ-2014-01273 |
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| 100 | 1 | _ | |a Maccarrone, Simona |0 P:(DE-Juel1)151337 |b 0 |e Corresponding author |
| 245 | _ | _ | |a Anchoring vs Bridging: New Findings on Polymer Additives in Bicontinuous Microemulsions |
| 260 | _ | _ | |a Washington, DC |c 2014 |b ACS Publ. |
| 336 | 7 | _ | |a Journal Article |b journal |m journal |0 PUB:(DE-HGF)16 |s 1425892997_22823 |2 PUB:(DE-HGF) |
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| 336 | 7 | _ | |a article |2 DRIVER |
| 520 | _ | _ | |a We show for the first time the effect of telechelic polymers asadditives in bicontinuous microemulsions. We combined macroscopicobservations of the phase behavior with microscopic measurements of thestructure by small-angle neutron scattering (SANS) to recover the two elasticmoduli, κ and κ̅, namely the bending rigidity and saddle-splay modulus. Onthe basis of these results, we could classify the effect of telechelic polymersalong with confinement, expressed as the ratio of the polymer end-to-enddistance Ree and the oil−water domain size d. Their unique property to anchorat two points in the membrane (bridging) acts like a switch from antiboosterto booster of the surfactant efficiency (between low and ultralowconfinement). In the region of medium confinement, all telechelic polymersare in the bridging configuration and we have a maximum of the boostingeffect, while at high confinement, the reversed behavior is found whereanchoring and/or bridging do not play any role anymore. |
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