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@ARTICLE{Zhukov:151786,
author = {Zhukov, Sergey and Kungl, Hans and Genenko, Yuri A. and von
Seggern, Heinz},
title = {{S}tatistical electric field and switching time
distributions in {PZT} 1{N}b2{S}r ceramics: {C}rystal- and
microstructure effects},
journal = {Journal of applied physics},
volume = {115},
issn = {1089-7550},
address = {Melville, NY},
publisher = {American Institute of Physics},
reportid = {FZJ-2014-01668},
pages = {014103},
year = {2014},
abstract = {Dispersive polarization response of ferroelectric PZT
ceramics is analyzed assuming theinhomogeneous field
mechanism of polarization switching. In terms of this model,
the localpolarization switching proceeds according to the
Kolmogorov-Avrami-Ishibashi scenario with theswitching time
determined by the local electric field. As a result, the
total polarization reversal isdominated by the statistical
distribution of the local field magnitudes. Microscopic
parameters of thismodel (the high-field switching time and
the activation field) as well as the statistical field
andconsequent switching time distributions due to disorder
at a mesoscopic scale can be directlydetermined from a set
of experiments measuring the time dependence of the total
polarizationswitching, when applying electric fields of
different magnitudes. PZT 1Nb2Sr ceramics with Zr/Tiratios
51.5/48.5, 52.25/47.75, and 60/40 with four different grain
sizes each were analyzed followingthis approach. Pronounced
differences of field and switching time distributions were
founddepending on the Zr/Ti ratios. Varying grain size also
affects polarization reversal parameters, but inanother way.
The field distributions remain almost constant with grain
size whereas switching timesand activation field tend to
decrease with increasing grain size. The quantitative
changes of the latterparameters with grain size are very
different depending on composition. The origin of the
effects onthe field and switching time distributions are
related to differences in structural and
microstructuralcharacteristics of the materials and are
discussed with respect to the hysteresis loops observed
underbipolar electrical cycling.},
cin = {IEK-9},
ddc = {530},
cid = {I:(DE-Juel1)IEK-9-20110218},
pnm = {152 - Renewable Energies (POF2-152) / 123 - Fuel Cells
(POF2-123)},
pid = {G:(DE-HGF)POF2-152 / G:(DE-HGF)POF2-123},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000329456300044},
doi = {10.1063/1.4860335},
url = {https://juser.fz-juelich.de/record/151786},
}