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@ARTICLE{Yoon:151821,
      author       = {Yoon, Songhak and Maegli, Alexandra E. and Karvonen, Lassi
                      and Shkabko, Andrey and Populoh, Sascha and Gałązka,
                      Krzysztof and Sagarna, Leyre and Aguirre, Myriam H. and
                      Jakes, Peter and Eichel, Rüdiger-A. and Ebbinghaus, Stefan
                      G. and Pokrant, Simone and Weidenkaff, Anke},
      title        = {{S}ynthesis, {C}rystal {S}tructure, {E}lectric and
                      {M}agnetic {P}roperties of {L}a{VO} 2.78 {N} 0.10},
      journal      = {Zeitschrift für anorganische und allgemeine Chemie},
      volume       = {640},
      number       = {5},
      issn         = {0044-2313},
      address      = {Weinheim},
      publisher    = {Wiley-VCH},
      reportid     = {FZJ-2014-01695},
      pages        = {797-804},
      year         = {2014},
      abstract     = {Perovskite-type LaVO2.78N0.10 powder was synthesized by
                      thermal ammonolysis of the oxide precursor LaVO4. By X-ray,
                      neutron, and electron diffraction an orthorhombic crystal
                      structure with space group Pnma was identified. XANES
                      spectra showed that the oxidation state of vanadium changes
                      from 5+ in LaVO4 to approximately 3+ in LaVO2.78N0.10. The
                      temperature dependence of the electrical conductivity
                      revealed an Arrhenius-type behavior with an activation
                      energy of 0.103 eV in the temperature range of 119–302 K
                      indicating that the conduction process is thermally
                      activated band transition. Based on the positive Seebeck
                      coefficient, holes were identified as the dominant charge
                      carriers in the temperature range of 100–302 K. Both the
                      Seebeck coefficient and the thermal conductivity showed an
                      anomaly at 138 K, which is attributed to the Néel
                      temperature for antiferromagnetic ordering according to
                      magnetic susceptibility measurements.},
      cin          = {IEK-9},
      ddc          = {540},
      cid          = {I:(DE-Juel1)IEK-9-20110218},
      pnm          = {123 - Fuel Cells (POF2-123) / 152 - Renewable Energies
                      (POF2-152)},
      pid          = {G:(DE-HGF)POF2-123 / G:(DE-HGF)POF2-152},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000333697200016},
      doi          = {10.1002/zaac.201300593},
      url          = {https://juser.fz-juelich.de/record/151821},
}