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000151898 1001_ $$0P:(DE-HGF)0$$aBoeddinghaus, M. Bele$$b0$$eCorresponding author
000151898 245__ $$aC 60 3- versus C 60 4- /C 60 2- - Synthesis and Characterization of Five Salts Containing Discrete Fullerene Anions
000151898 260__ $$aWeinheim$$bWiley-VCH$$c2014
000151898 3367_ $$0PUB:(DE-HGF)16$$2PUB:(DE-HGF)$$aJournal Article$$bjournal$$mjournal$$s1403098925_30221
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000151898 500__ $$aBitte POF III ergänzen. Vielen Dank.Early View, Keywords: Crystal structure determination; Fullerenes; Jahn-Teller effect; Magnetic properties; Polyanions
000151898 520__ $$aFive new compounds, [Rb(18crown-6)]3[C60] (1), [Rb(18crown-6)]6[C60]2(C3H7NO)2(C4H8O)2 (2), [Rb(benzo18crown-6)]6[C60]2(C2H8N2)5 (3), [Cs(benzo18crown-6)]3C60(C2H8N2)2 (4), and [Cs3(benzo18crown-6)5]C60(C2H8N2)(4.5+x) (5) were synthesized and characterized by single-crystal X-ray structure determination. All compounds contain discrete C60 anions, which are ordered in 1, 2, and 4, where direct cation-anion contacts occur. The unit cells of 1 and 2 contain two independent fullerides, which coordinate to the rubidium atoms either of two or of four [Rb(18crown-6)] units. Owing to the presence of differently coordinated fullerene units in compounds 1 and 2, a possible disproportionation of C603– into C602– and C604– anions is discussed. In 3 and 4 the C60 anions are coordinated by three Rb and Cs atoms, respectively. In all compounds the average charge of the anion is –3. Magnetic data reveal a doublet spin state for 3. The EPR spectra are discussed for compounds 3 and 5. The role of a dynamic Jahn-Teller distortion is discussed, and we report the first IR spectroscopic data of fullerene trianions, which have been obtained in solution.
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000151898 7001_ $$0P:(DE-HGF)0$$aKlein, Wilhelm$$b1
000151898 7001_ $$0P:(DE-HGF)0$$aWahl, Bernhard$$b2
000151898 7001_ $$0P:(DE-Juel1)156296$$aJakes, Peter$$b3$$ufzj
000151898 7001_ $$0P:(DE-Juel1)156123$$aEichel, Rüdiger-A.$$b4$$ufzj
000151898 7001_ $$0P:(DE-HGF)0$$aFässler, Thomas F.$$b5
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